CERN-LHC. In the $pp \rightarrow t\bar{t}$ process the angular distributions of top and anti-top quarks are expected to present a subtle difference, which could be enhanced by processes not included in the Standard Model. This Letter presents a measurement of the charge asymmetry in events where the top-quark pair is produced with a large invariant mass. The analysis is performed on 20.3 fb$^{-1}$ of $pp$ collision data at $\sqrt{s} =$ 8 TeV collected by the ATLAS experiment at the LHC, using reconstruction techniques specifically designed for the decay topology of highly boosted top quarks. The charge asymmetry in a fiducial region with large invariant mass of the top-quark pair ($m_{t\bar{t}} > $ 0.75 TeV) and an absolute rapidity difference of the top and anti-top quark candidates within $-$2 $ < |y_t| - |y_{\bar{t}}| <$ 2 is measured to be 4.2 $\pm$ 3.2%, in agreement with the Standard Model prediction at next-to-leading order. A differential measurement in three $t\bar{t}$ mass bins is also presented.