Signals consistent with the B$^+_\mathrm{c}$(2S) and B$^{*+}_\mathrm{c}$(2S) states are observed in proton-proton collisions at $\sqrt{s} =$ 13 TeV, in an event sample corresponding to an integrated luminosity of 140 fb$^{-1}$, collected by the CMS experiment during the 2016, 2017, and 2018 LHC running periods. These excited $\bar{\mathrm{b}}$c states are observed in the B$^+_\mathrm{c}\pi^+\pi^-$ invariant mass spectrum, with the ground state B$^+_\mathrm{c}$ reconstructed through its decay to J/$\psi\,\pi^+$. The two states are well resolved from each other and are observed with a significance exceeding five standard deviations. The mass of the B$^+_\mathrm{c}$(2S) meson is measured to be 6871.0 $\pm$ 1.2 (stat) $\pm$ 0.8 (syst) $\pm$ 0.8 (B$^+_\mathrm{c}$) MeV, where the last term corresponds to the uncertainty in the world-average B$^+_\mathrm{c}$ mass.
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