The study of (anti-)deuteron production in pp collisions has proven to be a powerful tool to investigate the formation mechanism of loosely bound states in high energy hadronic collisions. In this paper the production of (anti-)deuterons is studied as a function of the charged particle multiplicity in inelastic pp collisions at $\sqrt{s}=13$ TeV using the ALICE experiment. Thanks to the large number of accumulated minimum bias events, it has been possible to measure (anti-)deuteron production in pp collisions up to the same charged particle multiplicity ($\rm{d} N_{ch}/\rm{d}\eta\sim26$) as measured in p-Pb collisions at similar centre-of-mass energies. Within the uncertainties, the deuteron yield in pp collisions resembles the one in p-Pb interactions, suggesting a common formation mechanism behind the production of light nuclei in hadronic interactions. In this context the measurements are compared with the expectations of coalescence and Statistical Hadronisation Models (SHM).

The production cross sections of the prompt charmed mesons D$^0$, D$^+$, D$^{*+}$ and D$_s$ were measured at mid-rapidity in p-Pb collisions at a centre-of-mass energy per nucleon pair $\sqrt{s_{\rm NN}}=5.02$ TeV with the ALICE detector at the LHC. D mesons were reconstructed from their decays D$^0\rightarrow{\rm K}^-\pi^+$, D$^+\rightarrow{\rm K}^-\pi^+\pi^+$, D$^{*+}\rightarrow D^0\pi^+$, D$_s^+\rightarrow\phi\pi^+\rightarrow{\rm K}^-{\rm K}^+\pi^+$, and their charge conjugates. The $p_{\rm T}$-differential production cross sections were measured at mid-rapidity in the interval $1<p_{\rm T}<24$ GeV/$c$ for D$^0$, D$^+$ and D$^{*+}$ mesons and in $2<p_{\rm T}<12$ GeV/$c$ for D$_s$ mesons, using an analysis method based on the selection of decay topologies displaced from the interaction vertex. The production cross sections of the D$^0$, D$^+$ and D$^{*+}$ mesons were also measured in three $p_{\rm T}$ intervals as a function of the rapidity $y_{\rm cms}$ in the centre-of-mass system in $-1.26<y_{\rm cms}<0.34$. In addition, the prompt D$^0$ cross section was measured in pp collisions at $\sqrt{s}=7$ TeV and p-Pb collisions at $\sqrt{s_{\rm NN}}=5.02$ TeV down to $p_{\rm T}=0$ using an analysis technique that is based on the estimation and subtraction of the combinatorial background, without reconstruction of the D$^0$ decay vertex. The nuclear modification factor $R_{\rm pPb}(p_{\rm T})$, defined as the ratio of the $p_{\rm T}$-differential D-meson cross section in p-Pb collisions and that in pp collisions scaled by the mass number of the Pb nucleus, was calculated for the four D-meson species and found to be compatible with unity within experimental uncertainties. The results are compared to theoretical calculations that include cold-nuclear-matter effects and to transport model calculations incorporating the interactions of charm quarks with an expanding deconfined medium.

This article reports measurements characterizing the Underlying Event (UE) associated with hard scatterings at midrapidity in pp collisions at $\sqrt{s}=13$ TeV. The hard scatterings are identified by the leading particle, the charged particle with the highest transverse momentum ($p_{\rm T}^{\rm leading}$) in the event. Charged-particle number and summed transverse-momentum densities are measured in different azimuthal regions defined with respect to the leading particle direction: Toward, Transverse, and Away. The Toward and Away regions contain the fragmentation products of the hard scatterings in addition to the UE contribution, whereas particles in the Transverse region are expected to originate predominantly from the UE. The study is performed as a function of $p_{\rm T}^{\rm leading}$ with three different $p_{\rm T}$ thresholds for the associated particles, $p_{\rm T}^{\rm min} >$ 0.15, 0.5, and 1.0 GeV/$c$. The charged-particle density in the Transverse region rises steeply for low values of $p_{\rm T}^{\rm leading}$ and reaches a plateau. The results confirm the trend that the charged-particle density in the Transverse region shows a stronger increase with $\sqrt{s}$ than the inclusive charged-particle density at midrapidity. The UE activity is increased by approximately 20% when going from 7 to 13 TeV. The plateau in the Transverse region ($5 < p_{\rm T}^{\rm leading} < ~ 40$ GeV/$c$ ) is further characterized by the probability distribution of its charged-particle multiplicity normalized to its average value (relative transverse activity, $R_{T}$) and the mean transverse momentum as a function of $R_{T}$. Experimental results are compared to model calculations using PYTHIA 8 and EPOS LHC. The overall agreement between models and data is within 30%. These measurements provide new insights on the interplay between hard scatterings and the associated UE in pp collisions.

The first measurement of e$^+$e$^-$ pair production at mid-rapidity ($|\eta_{{\rm e}}|$ $<$ 0.8) in pp collisions at $\sqrt{s} = 7$ TeV with ALICE at the LHC is presented. The dielectron production is studied as a function of the invariant mass ($m_{\rm ee}$ $<$ 3.3 GeV/$c^{2}$), the pair transverse momentum ($p_{\rm T,ee}$ $<$ 8 GeV/$c$), and the pair transverse impact parameter (DCA$_{{\rm ee}}$), i.e., the average distance of closest approach of the reconstructed electron and positron tracks to the collision vertex, normalised to its resolution. The results are compared with the expectations from a cocktail of known hadronic sources and are well described when PYTHIA is used to generate the heavy-flavour contributions. In the low-mass region (0.14 $<$ $m_{\rm ee}$ $<$ 1.1 GeV/$c^{2}$), prompt and non-prompt e$^+$e$^-$ sources can be separated via the DCA$_{\rm ee}$. In the intermediate-mass region (1.1 $<$ $m_{\rm ee}$ $<$ 2.7 GeV/$c^{2}$), a double-differential fit to the data in $m_{\rm ee}$ and $p_{\rm T,ee}$ and a fit of the DCA$_{\rm ee}$ distribution allow the total ${\rm c\overline c}$ and ${\rm b\overline b}$ cross sections to be extracted. Two different event generators, PYTHIA and POWHEG, can reproduce the shape of the two-dimensional $m_{\rm ee}$ and $p_{\rm T,ee}$ spectra, as well as the shape of the DCA$_{\rm ee}$ distribution, reasonably well. However, differences in the ${\rm c\overline c}$ and ${\rm b\overline b}$ cross sections are observed when using the generators to extrapolate to full phase space. Finally, the ratio of inclusive to decay photons is studied via the measurement of virtual direct photons in the transverse-momentum range 1 $<$ $p_{\rm T}$ $<$ 8 GeV/$c$. This is found to be unity within the statistical and systematic uncertainties and consistent with expectations from next-to-leading order perturbative quantum chromodynamic calculations.

The $p_{\rm T}$-differential production cross section of prompt $\Lambda_{\rm c}^+$ charmed baryons was measured with the ALICE detector at the Large Hadron Collider (LHC) in pp collisions at $\sqrt{s} = 7$ TeV and in p-Pb collisions at $\sqrt{s_{\rm NN}} = 5.02$ TeV at midrapidity. The $\Lambda_{\rm c}^+$ and ${\overline{\Lambda}}_{\rm c}^-$ were reconstructed in the hadronic decay modes $\Lambda_{\rm c}^+\rightarrow {\rm p}{\rm K^-}\pi^+$, $\Lambda_{\rm c}^+\rightarrow {\rm p}{\rm K_{\rm S}^0}$ and in the semileptonic channel $\Lambda_{\rm c}^+\rightarrow {\rm e^+}\nu_{\rm e}\Lambda$ (and charge conjugates). The measured values of the $\Lambda_{\rm c}^+/{\rm D_0}$ ratio, which is sensitive to the c-quark hadronisation mechanism, and in particular to the production of baryons, are presented and are larger than those measured previously in different colliding systems, centre-of-mass energies, rapidity and $p_{\rm T}$ intervals, where the $\Lambda_{\rm c}^+$ production process may differ. The results are compared with the expectations obtained from perturbative Quantum Chromodynamics calculations and Monte Carlo event generators. Neither perturbative QCD calculations nor Monte Carlo models reproduce the data, indicating that the fragmentation of heavy-flavour baryons is not well understood. The first measurement at the LHC of the $\Lambda_{\rm c}^+$ nuclear modification factor, $R_{\rm pPb}$, is also presented. The $R_{\rm pPb}$ is found to be consistent with unity and with that of D mesons within the uncertainties, and consistent with a theoretical calculation that includes cold nuclear matter effects and a calculation that includes charm quark interactions with a deconfined medium.

At sufficiently high temperature and energy density, nuclear matter undergoes a transition to a phase in which quarks and gluons are not confined: the Quark-Gluon Plasma (QGP) [1]. Such an extreme state of strongly-interacting QCD (Quantum Chromo-Dynamics) matter is produced in the laboratory with high-energy collisions of heavy nuclei, where an enhanced production of strange hadrons is observed [2-6]. Strangeness enhancement, originally proposed as a signature of QGP formation in nuclear collisions [7], is more pronounced for multi-strange baryons. Several effects typical of heavy-ion phenomenology have been observed in high-multiplicity proton-proton (pp) collisions [8,9]. Yet, enhanced production of multi-strange particles has not been reported so far. Here we present the first observation of strangeness enhancement in high-multiplicity pp collisions. We find that the integrated yields of strange and multi-strange particles relative to pions increases significantly with the event charged-particle multiplicity. The measurements are in remarkable agreement with p-Pb collision results [10,11] indicating that the phenomenon is related to the final system created in the collision. In high-multiplicity events strangeness production reaches values similar to those observed in Pb-Pb collisions, where a QGP is formed.

This Letter presents the first direct investigation of the p-$\Sigma^{0}$ interaction, using the femtoscopy technique in high-multiplicity pp collisions at $\sqrt{s}$ = 13 TeV measured by the ALICE detector. The $\Sigma^{0}$ is reconstructed via the decay channel to $\Lambda \gamma$, and the subsequent decay of $\Lambda$ to p$\pi^-$. The photon is detected via the conversion in material to e$^{+}$e$^{-}$ pairs exploiting the unique capability of the ALICE detector to measure electrons at low transverse momenta. The measured p-$\Sigma^{0}$ correlation indicates a shallow strong interaction. The comparison of the data to several theoretical predictions obtained employing the $Correlation~Analysis~Tool~using~the~Schr\"odinger~Equation$ (CATS) and the Lednick\'y-Lyuboshits approach shows that the current experimental precision does not yet allow to discriminate between different models, as it is the case for the available scattering and hypernuclei data. Nevertheless, the p-$\Sigma^{0}$ correlation function is found to be sensitive to the strong interaction, and driven by the interplay of the different spin and isospin channels. This pioneering study demonstrates the feasibility of a femtoscopic measurement in the p-$\Sigma^{0}$ channel and with the expected larger data samples in LHC Run 3 and Run 4, the p-$\Sigma^{0}$ interaction will be constrained with high precision.

The first evidence of spin alignment of vector mesons ($K^{*0}$ and $\phi$) in heavy-ion collisions at the Large Hadron Collider (LHC) is reported. The spin density matrix element $\rho_{00}$ is measured at midrapidity ($|y| <$ 0.5) in Pb-Pb collisions at a center-of-mass energy ($\sqrt{s_{\rm NN}}$) of 2.76 TeV with the ALICE detector. $\rho_{00}$ values are found to be less than 1/3 (1/3 implies no spin alignment) at low transverse momentum ($p_{\rm T} <$ 2 GeV/$c$) for $K^{*0}$ and $\phi$ at a level of 3$\sigma$ and 2$\sigma$, respectively. No significant spin alignment is observed for the $K^0_S$ meson (spin = 0) in Pb-Pb collisions and for the vector mesons in $pp$ collisions. The measured spin alignment is unexpectedly large but qualitatively consistent with the expectation from models which attribute it to a polarization of quarks in the presence of angular momentum in heavy-ion collisions and a subsequent hadronization by the process of recombination.

We present the results of three-dimensional femtoscopic analyses for charged and neutral kaons recorded by ALICE in Pb-Pb collisions at $\sqrt{s_{\rm{NN}}}$ = 2.76 TeV. Femtoscopy is used to measure the space-time characteristics of particle production from the effects of quantum statistics and final-state interactions in two-particle correlations. Kaon femtoscopy is an important supplement to that of pions because it allows one to distinguish between different model scenarios working equally well for pions. In particular, we compare the measured 3D kaon radii with a purely hydrodynamical calculation and a model where the hydrodynamic phase is followed by a hadronic rescattering stage. The former predicts an approximate transverse mass ($m_{\mathrm{T}}$) scaling of source radii obtained from pion and kaon correlations. This $m_{\mathrm{T}}$ scaling appears to be broken in our data, which indicates the importance of the hadronic rescattering phase at LHC energies. A $k_{\mathrm{T}}$ scaling of pion and kaon source radii is observed instead. The time of maximal emission of the system is estimated using the three-dimensional femtoscopic analysis for kaons. The measured emission time is larger than that of pions. Our observation is well supported by the hydrokinetic model predictions.

The azimuthal correlations of D mesons and charged particles were measured with the ALICE detector in pp collisions at $\sqrt{s}=7$ TeV and p-Pb collisions at $\sqrt{s_{\rm NN}}=5.02$ TeV at the Large Hadron Collider. D$^0$, D$^+$, and D$^{*+}$ mesons and their charge conjugates with transverse momentum $3<p_{\rm T}<16$ GeV/$c$ and rapidity in the nucleon-nucleon centre-of-mass system $|y_{\rm cms}|<0.5$ (pp collisions) and $-0.96<y_{\rm cms}<0.04$ (p-Pb collisions) were correlated to charged particles with $p_{\rm T}>0.3$ Gev/$c$. The properties of the correlation peak induced by the jet containing the D meson, described in terms of the yield of charged particles in the peak and peak width, are compatible within uncertainties between the two collision systems, and described by Monte-Carlo simulations based on the PYTHIA, POWHEG and EPOS 3 event generators.