The study of (anti-)deuteron production in pp collisions has proven to be a powerful tool to investigate the formation mechanism of loosely bound states in high energy hadronic collisions. In this paper the production of (anti-)deuterons is studied as a function of the charged particle multiplicity in inelastic pp collisions at $\sqrt{s}=13$ TeV using the ALICE experiment. Thanks to the large number of accumulated minimum bias events, it has been possible to measure (anti-)deuteron production in pp collisions up to the same charged particle multiplicity ($\rm{d} N_{ch}/\rm{d}\eta\sim26$) as measured in p-Pb collisions at similar centre-of-mass energies. Within the uncertainties, the deuteron yield in pp collisions resembles the one in p-Pb interactions, suggesting a common formation mechanism behind the production of light nuclei in hadronic interactions. In this context the measurements are compared with the expectations of coalescence and Statistical Hadronisation Models (SHM).

This article reports measurements characterizing the Underlying Event (UE) associated with hard scatterings at midrapidity in pp collisions at $\sqrt{s}=13$ TeV. The hard scatterings are identified by the leading particle, the charged particle with the highest transverse momentum ($p_{\rm T}^{\rm leading}$) in the event. Charged-particle number and summed transverse-momentum densities are measured in different azimuthal regions defined with respect to the leading particle direction: Toward, Transverse, and Away. The Toward and Away regions contain the fragmentation products of the hard scatterings in addition to the UE contribution, whereas particles in the Transverse region are expected to originate predominantly from the UE. The study is performed as a function of $p_{\rm T}^{\rm leading}$ with three different $p_{\rm T}$ thresholds for the associated particles, $p_{\rm T}^{\rm min} >$ 0.15, 0.5, and 1.0 GeV/$c$. The charged-particle density in the Transverse region rises steeply for low values of $p_{\rm T}^{\rm leading}$ and reaches a plateau. The results confirm the trend that the charged-particle density in the Transverse region shows a stronger increase with $\sqrt{s}$ than the inclusive charged-particle density at midrapidity. The UE activity is increased by approximately 20% when going from 7 to 13 TeV. The plateau in the Transverse region ($5 < p_{\rm T}^{\rm leading} < ~ 40$ GeV/$c$ ) is further characterized by the probability distribution of its charged-particle multiplicity normalized to its average value (relative transverse activity, $R_{T}$) and the mean transverse momentum as a function of $R_{T}$. Experimental results are compared to model calculations using PYTHIA 8 and EPOS LHC. The overall agreement between models and data is within 30%. These measurements provide new insights on the interplay between hard scatterings and the associated UE in pp collisions.

This Letter presents the first direct investigation of the p-$\Sigma^{0}$ interaction, using the femtoscopy technique in high-multiplicity pp collisions at $\sqrt{s}$ = 13 TeV measured by the ALICE detector. The $\Sigma^{0}$ is reconstructed via the decay channel to $\Lambda \gamma$, and the subsequent decay of $\Lambda$ to p$\pi^-$. The photon is detected via the conversion in material to e$^{+}$e$^{-}$ pairs exploiting the unique capability of the ALICE detector to measure electrons at low transverse momenta. The measured p-$\Sigma^{0}$ correlation indicates a shallow strong interaction. The comparison of the data to several theoretical predictions obtained employing the $Correlation~Analysis~Tool~using~the~Schr\"odinger~Equation$ (CATS) and the Lednick\'y-Lyuboshits approach shows that the current experimental precision does not yet allow to discriminate between different models, as it is the case for the available scattering and hypernuclei data. Nevertheless, the p-$\Sigma^{0}$ correlation function is found to be sensitive to the strong interaction, and driven by the interplay of the different spin and isospin channels. This pioneering study demonstrates the feasibility of a femtoscopic measurement in the p-$\Sigma^{0}$ channel and with the expected larger data samples in LHC Run 3 and Run 4, the p-$\Sigma^{0}$ interaction will be constrained with high precision.

A measurement of dielectron production in proton-proton (pp) collisions at $\sqrt{s} = 13$ TeV, recorded with the ALICE detector at the CERN LHC, is presented in this Letter. The data set was recorded with a reduced magnetic solenoid field. This enables the investigation of a kinematic domain at low dielectron invariant mass $m_{\rm ee}$ and pair transverse momentum $p_{\rm T,ee}$ that was previously inaccessible at the LHC. The cross section for dielectron production is studied as a function of $m_{\rm ee}$, $p_{\rm T,ee}$, and event multiplicity ${\rm d} N_{\rm ch}/{\rm d} \eta$. The expected dielectron rate from hadron decays, called hadronic cocktail, utilizes a parametrization of the measured $\eta/\pi^0$ ratio in pp and proton-nucleus (p-A) collisions, assuming that this ratio shows no strong dependence on collision energy at low transverse momentum. Comparison of the measured dielectron yield to the hadronic cocktail at $0.15<m_{\rm ee}<0.6$ GeV/$c^2$ and for $p_{\rm T,ee} < 0.4$ GeV/$c$ indicates an enhancement of soft dielectrons, reminiscent of the 'anomalous' soft-photon and -dilepton excess in hadron-hadron collisions reported by several experiments under different experimental conditions. The enhancement factor over the hadronic cocktail amounts to $1.61\pm 0.13\,(\rm{stat.})\pm 0.17\,(\rm{syst., data}) \pm 0.34\,(\rm{syst., cocktail})$ in the ALICE acceptance. Acceptance-corrected excess spectra in $m_{\rm ee}$ and $p_{\rm T,ee}$ are extracted and compared with calculations of dielectron production from hadronic bremsstrahlung and thermal radiation within a hadronic many-body approach.

The cross section of jets reconstructed from charged particles is measured in the transverse momentum range of $5<p_\mathrm{T}<100\ \mathrm{GeV}/c$ in pp collisions at the center-of-mass energy of $\sqrt{s} = 5.02\ \mathrm{TeV}$ with the ALICE detector. The jets are reconstructed using the anti-$k_\mathrm{T}$ algorithm with resolution parameters $R=0.2$, $0.3$, $0.4$, and $0.6$ in the pseudorapidity range $|\eta|< 0.9-R$. The charged jet cross sections are compared with the leading order (LO) and to next-to-leading order (NLO) perturbative Quantum ChromoDynamics (pQCD) calculations. It was found that the NLO calculations agree better with the measurements. The cross section ratios for different resolution parameters were also measured. These ratios increase from low $p_\mathrm{T}$ to high $p_\mathrm{T}$ and saturate at high $p_\mathrm{T}$, indicating that jet collimation is larger at high $p_\mathrm{T}$ than at low $p_\mathrm{T}$. These results provide a precision test of pQCD predictions and serve as a baseline for the measurement in Pb$-$Pb collisions at the same energy to quantify the effects of the hot and dense medium created in heavy-ion collisions at the LHC.

The study of the strength and behaviour of the antikaon-nucleon ($\mathrm{\overline{K}N}$) interaction constitutes one of the key focuses of the strangeness sector in low-energy Quantum Chromodynamics (QCD). In this letter a unique high-precision measurement of the strong interaction between kaons and protons, close and above the kinematic threshold, is presented. The femtoscopic measurements of the correlation function at low pair-frame relative momentum of (K$^+$ p $\oplus$ K$^-$ $\overline{\mathrm{p}}$) and (K$^-$ p $\oplus$ K$^+$ $\overline{\mathrm{p}}$) pairs measured in pp collisions at $\sqrt{s}$ = 5, 7 and 13 TeV are reported. A structure observed around a relative momentum of 58 MeV/$c$ in the measured correlation function of (K$^-$ p $\oplus$ K$^+$ $\overline{\mathrm{p}}$) with a significance of 4.4. $\sigma$ constitutes the first experimental evidence for the opening of the $(\mathrm{\overline{K}^0 n} \oplus \mathrm{K^0 \overline{n}})$ isospin breaking channel due to the mass difference between charged and neutral kaons. The measured correlation functions have been compared to J\"{u}lich and Kyoto models in addition to the Coulomb potential. The high-precision data at low relative momenta presented in this work prove femtoscopy to be a powerful complementary tool to scattering experiments and provide new constraints above the $\mathrm{\overline{K}N}$ threshold for low-energy QCD chiral models.

Measurements of the production cross sections of prompt ${\rm D^0}$, ${\rm D^+}$, ${\rm D^{\ast +}}$, ${\rm D_s^+}$, ${\rm \Lambda_{c}^{+}}$, and ${\rm \Xi_{c}^{+}}$ charm hadrons at midrapidity in proton$-$proton collisions at $\sqrt{s}=13$ TeV with the ALICE detector are presented. The D-meson cross sections as a function of transverse momentum ($p_{\rm T}$) are provided with improved precision and granularity. The ratios of $p_{\rm T}$-differential meson production cross sections based on this publication and on measurements at different rapidity and collision energy provide a constraint on gluon parton distribution functions at low values of Bjorken-$x$ ($10^{-5}-10^{-4}$). The measurements of ${\rm \Lambda_{c}^{+}}$ (${\rm \Xi_{c}^{+}}$) baryon production extend the measured $p_{\rm T}$ intervals down to $p_{\rm T}=0(3)$~GeV$/c$. These measurements are used to determine the charm-quark fragmentation fractions and the ${\rm c\overline{c}}$ production cross section at midrapidity ($|y|<0.5$) based on the sum of the cross sections of the weakly-decaying ground-state charm hadrons ${\rm D^0}$, ${\rm D^+}$, ${\rm D_s^+}$, ${\rm \Lambda_{c}^{+}}$, ${\rm \Xi_{c}^{0}}$ and, for the first time, ${\rm \Xi_{c}^{+}}$, and of the strongly-decaying J/$psi$ mesons. The first measurements of ${\rm \Xi_{c}^{+}}$ and ${\rm \Sigma_{c}^{0,++}}$ fragmentation fractions at midrapidity are also reported. A significantly larger fraction of charm quarks hadronising to baryons is found compared to e$^+$e$^-$ and ep collisions. The ${\rm c\overline{c}}$ production cross section at midrapidity is found to be at the upper bound of state-of-the-art perturbative QCD calculations.

Measurements of the inclusive J/$\psi$ yield as a function of charged-particle pseudorapidity density ${\rm d}N_{\rm ch}/\rm{d}\eta$ in pp collisions at $\sqrt{s}$ = 13 TeV with ALICE at the LHC are reported. The J/$\psi$ meson yield is measured at midrapidity ($|y|<0.9$) in the dielectron channel, for events selected based on the charged-particle multiplicity at midrapidity ($|\eta|<1$) and at forward rapidity ($-3.7<\eta<-1.7$ and $2.8<\eta<5.1$); both observables are normalized to their corresponding averages in minimum bias events. The increase of the normalized J/$\psi$ yield with normalized ${\rm d}N_{\rm ch}/\rm{d}\eta$ is significantly stronger than linear and dependent on the transverse momentum. The data are compared to theoretical predictions, which describe the observed trends well, albeit not always quantitatively.

The production rates and the transverse momentum distribution of strange hadrons at mid-rapidity ($\ |y\ | < 0.5$) are measured in proton-proton collisions at $\sqrt{s}$ = 13 TeV as a function of the charged particle multiplicity, using the ALICE detector at the LHC. The production rates of $\rm{K}^{0}_{S}$, $\Lambda$, $\Xi$, and $\Omega$ increase with the multiplicity faster than what is reported for inclusive charged particles. The increase is found to be more pronounced for hadrons with a larger strangeness content. Possible auto-correlations between the charged particles and the strange hadrons are evaluated by measuring the event-activity with charged particle multiplicity estimators covering different pseudorapidity regions. When comparing to lower energy results, the yields of strange hadrons are found to depend only on the mid-rapidity charged particle multiplicity. Several features of the data are reproduced qualitatively by general purpose QCD Monte Carlo models that take into account the effect of densely-packed QCD strings in high multiplicity collisions. However, none of the tested models reproduce the data quantitatively. This work corroborates and extends the ALICE findings on strangeness production in proton-proton collisions at 7 TeV.

This paper presents the measurements of $\pi^{\pm}$, $\rm{K}^{\pm}$, $\rm{p}$ and $\bar{\rm{p}}$ transverse momentum ($p_{\rm{T}}$) spectra as a function of charged-particle multiplicity density in proton-proton (pp) collisions at $\sqrt{s}$ = 13 TeV with the ALICE detector at the LHC. Such study allows us to isolate the center-of-mass energy dependence of light-flavour particle production. The measurements reported here cover a $p_{\rm{T}}$ range from 0.1 GeV/$c$ to 20 GeV/$c$ and are done in the rapidity interval $|y|<0.5$. The $p_{\rm{T}}$-differential particle ratios exhibit an evolution with multiplicity, similar to that observed in pp collisions at $\sqrt{s}$ = 7 TeV, which is qualitatively described by some of the hydrodynamical and pQCD-inspired models discussed in this paper. Furthermore, the $p_{\rm{T}}$-integrated hadron-to-pion yield ratios measured in pp collisions at two different center-of-mass energies are consistent when compared at similar multiplicities. This also extends to strange and multistrange hadrons, suggesting that, at LHC energies, particle hadrochemistry scales with particle multiplicity the same way under different collision energies and colliding systems.