The study of (anti-)deuteron production in pp collisions has proven to be a powerful tool to investigate the formation mechanism of loosely bound states in high energy hadronic collisions. In this paper the production of (anti-)deuterons is studied as a function of the charged particle multiplicity in inelastic pp collisions at $\sqrt{s}=13$ TeV using the ALICE experiment. Thanks to the large number of accumulated minimum bias events, it has been possible to measure (anti-)deuteron production in pp collisions up to the same charged particle multiplicity ($\rm{d} N_{ch}/\rm{d}\eta\sim26$) as measured in p-Pb collisions at similar centre-of-mass energies. Within the uncertainties, the deuteron yield in pp collisions resembles the one in p-Pb interactions, suggesting a common formation mechanism behind the production of light nuclei in hadronic interactions. In this context the measurements are compared with the expectations of coalescence and Statistical Hadronisation Models (SHM).

Understanding the production mechanism of light (anti)nuclei is one of the key challenges of nuclear physics and has important consequences for astrophysics, since it provides an input for indirect dark-matter searches in space. In this paper, the latest results about the production of light (anti)nuclei in pp collisions at $\sqrt{s} = 13$ TeV are presented, focusing on the comparison with the predictions of coalescence and thermal models. For the first time, the coalescence parameters $B_2$ for deuterons and $B_3$ for helions are compared with parameter-free theoretical predictions that are directly constrained by the femtoscopic measurement of the source radius in the same event class. A fair description of the data with a Gaussian wave function is observed for both deuteron and helion, supporting the coalescence mechanism for the production of light (anti)nuclei in pp collisions. This method paves the way for future investigations of the internal structure of more complex nuclear clusters, including the hypertriton.

The study of the production of nuclei and antinuclei in pp collisions has proven to be a powerful tool to investigate the formation mechanism of loosely bound states in high-energy hadronic collisions. In this paper, the production of protons, deuterons and $^3$He and their charge conjugates at midrapidity is studied as a function of the charged-particle multiplicity in inelastic pp collisions at $\sqrt{s}=5.02$ TeV using the ALICE detector. Within the uncertainties, the yields of nuclei in pp collisions at $\sqrt{s}=5.02$ TeV are compatible with those in pp collisions at different energies and to those in p-Pb collisions when compared at similar multiplicities. The measurements are compared with the expectations of coalescence and Statistical Hadronisation Models. The results suggest a common formation mechanism behind the production of light nuclei in hadronic interactions and confirm that they do not depend on the collision energy but on the number of produced particles.

In this letter, the production of deuterons and anti-deuterons in pp collisions at $\sqrt{s} = 7$ TeV is studied as a function of the charged-particle multiplicity density at mid-rapidity with the ALICE detector at the LHC. Production yields are measured at mid-rapidity in five multiplicity classes and as a function of the deuteron transverse momentum ($p_{\rm{T}}$). The measurements are discussed in the context of hadron-coalescence models. The coalescence parameter $B_{2}$, extracted from the measured spectra of (anti-)deuterons and primary (anti-)protons, exhibits no significant $p_{\rm{T}}$-dependence for $p_{\rm{T}} < 3$ GeV/$c$, in agreement with the expectations of a simple coalescence picture. At fixed transverse momentum per nucleon, the $B_{2}$ parameter is found to decrease smoothly from low multiplicity pp Pb-Pb collisions, in qualitative agreement with more elaborate coalescence models. The measured mean transverse momentum of (anti-)deuterons in pp is not reproduced by the Blast-Wave model calculations that simultaneously describe pion, kaon and proton spectra, in contrast to central Pb-Pb collisions. The ratio between the $p_{\rm{T}}$-integrated yield of deuterons to protons, d/p, is found to increase with the charged-particle multiplicity, as observed in inelastic pp collisions at different centre-of-mass energies. The d/p ratios are reported in a wide range, from the lowest to the highest multiplicity values measured in pp collisions at the LHC.

We have measured the distributions of protons and deuterons produced in high energy heavy ion Au+Au collisions at RHIC over a very wide range of transverse and longitudinal momentum. Near mid-rapidity we have also measured the distribution of anti-protons and anti-deuterons. We present our results in the context of coalescence models. In particular we extract the "volume of homogeneity" and the average phase-space density for protons and anti-protons. Near central rapidity the coalescence parameter $B_2(p_T)$ and the space averaged phase-space density $<f> (p_T)$ are very similar for both protons and anti-protons. For protons we see little variation of either $B_2(p_T)$ or the space averaged phase-space density as the rapidity increases from 0 to 3. However both these quantities depend strongly on $p_T$ at all rapidities. These results are in contrast to lower energy data where the proton and anti-proton phase-space densities are different at $y$=0 and both $B_2$ and $f$ depend strongly on rapidity.

Measurements of (anti)proton, (anti)deuteron, and (anti)$^3$He production in the rapidity range $-1<y< 0$ as a function of the transverse momentum and event multiplicity in p-Pb collisions at a center-of-mass energy per nucleon-nucleon pair $\sqrt{s_{\rm NN}} = 8.16$ TeV are presented. The coalescence parameters $B_2$ and $B_3$, measured as a function of the transverse momentum per nucleon and of the mean charged-particle multiplicity density, confirm a smooth evolution from low to high multiplicity across different collision systems and energies. The ratios between (anti)deuteron and (anti)$^3$He yields and those of (anti)protons are also reported as a function of the mean charged-particle multiplicity density. A comparison with the predictions of the statistical hadronization and coalescence models for different collision systems and center-of-mass energies favors the coalescence description for the deuteron-to-proton yield ratio with respect to the canonical statistical model.

The production of the hypertriton nuclei $^{3}_{\Lambda}\mathrm H$ and $^{3}_{\bar{\Lambda}} \overline{\mathrm H}$ has been measured for the first time in Pb-Pb collisions at $\sqrt{s_{\rm NN}}$ = 2.76 TeV with the ALICE experiment at LHC energies. The total yield, d$N$/d$y$ $\times \mathrm{B.R.}_{\left( ^{3}_{\Lambda}\mathrm H \rightarrow ^{3}\mathrm{He},\pi^{-} \right)} = \left( 3.86 \pm 0.77 (\mathrm{stat.}) \pm 0.68 (\mathrm{syst.})\right) \times 10^{-5}$ in the 0-10% most central collisions, is consistent with the predictions from a statistical thermal model using the same temperature as for the light hadrons. The coalescence parameter $B_3$ shows a dependence on the transverse momentum, similar to the $B_2$ of deuterons and the $B_3$ of $^{3}\mathrm{He}$ nuclei. The ratio of yields $S_3$ = $^{3}_{\Lambda}\mathrm H$/($^{3}\mathrm{He}$ $\times \Lambda/\mathrm{p}$) was measured to be $S_3$ = 0.60 $\pm$ 0.13 (stat.) $\pm$ 0.21 (syst.) in 0-10% centrality events; this value is compared to different theoretical models. The measured $S_3$ is fully compatible with thermal model predictions. The measured $^{3}_{\Lambda}\mathrm H$ lifetime, $ \tau = 181^{+54}_{-39} (\mathrm{stat.}) \pm 33 (\mathrm{syst.})\ \mathrm{ps}$ is compatible within 1$\sigma$ with the world average value.

Invariant differential yields of deuterons and anti-deuterons in pp collisions at $\sqrt{s}$ = 0.9, 2.76 and 7 TeV and the yields of tritons, $^{3}$He nuclei and their anti-nuclei at $\sqrt{s}$ = 7 TeV have been measured with the ALICE detector at the LHC. The measurements cover a wide transverse momentum ($p_{\text{T}}$) range in the rapidity interval $|y|<0.5$, extending both the energy and the $p_{\text{T}}$ reach of previous measurements up to 3 GeV/$c$ for $A=2$ and 6 GeV/$c$ for $A=3$. The coalescence parameters of (anti-)deuterons and $^{3}\overline{\text{He}}$ nuclei exhibit an increasing trend with $p_{\text{T}}$ and are found to be compatible with measurements in pA collisions at low $p_{\text{T}}$ and lower energies. The integrated yields decrease by a factor of about 1000 for each increase of the mass number with one (anti-)nucleon. Furthermore, the deuteron-to-proton ratio is reported as a function of the average charged particle multiplicity at different center-of-mass energies.

Production of $d$, $t$, and $^3$He nuclei in central Pb+Pb interactions was studied at five collision energies ($\sqrt{s_{NN}}=$ 6.3, 7.6, 8.8, 12.3, and 17.3 GeV) with the NA49 detector at the CERN SPS. Transverse momentum spectra, rapidity distributions, and particle ratios were measured. Yields are compared to predictions of statistical models. Phase-space distributions of light nuclei are discussed and compared to those of protons in the context of a coalescence approach. The coalescence parameters $B_2$ and $B_3$, as well as coalescence radii for $d$ and $^3$He were determined as a function of transverse mass at all energies.