The study of (anti-)deuteron production in pp collisions has proven to be a powerful tool to investigate the formation mechanism of loosely bound states in high energy hadronic collisions. In this paper the production of (anti-)deuterons is studied as a function of the charged particle multiplicity in inelastic pp collisions at $\sqrt{s}=13$ TeV using the ALICE experiment. Thanks to the large number of accumulated minimum bias events, it has been possible to measure (anti-)deuteron production in pp collisions up to the same charged particle multiplicity ($\rm{d} N_{ch}/\rm{d}\eta\sim26$) as measured in p-Pb collisions at similar centre-of-mass energies. Within the uncertainties, the deuteron yield in pp collisions resembles the one in p-Pb interactions, suggesting a common formation mechanism behind the production of light nuclei in hadronic interactions. In this context the measurements are compared with the expectations of coalescence and Statistical Hadronisation Models (SHM).

At sufficiently high temperature and energy density, nuclear matter undergoes a transition to a phase in which quarks and gluons are not confined: the Quark-Gluon Plasma (QGP) [1]. Such an extreme state of strongly-interacting QCD (Quantum Chromo-Dynamics) matter is produced in the laboratory with high-energy collisions of heavy nuclei, where an enhanced production of strange hadrons is observed [2-6]. Strangeness enhancement, originally proposed as a signature of QGP formation in nuclear collisions [7], is more pronounced for multi-strange baryons. Several effects typical of heavy-ion phenomenology have been observed in high-multiplicity proton-proton (pp) collisions [8,9]. Yet, enhanced production of multi-strange particles has not been reported so far. Here we present the first observation of strangeness enhancement in high-multiplicity pp collisions. We find that the integrated yields of strange and multi-strange particles relative to pions increases significantly with the event charged-particle multiplicity. The measurements are in remarkable agreement with p-Pb collision results [10,11] indicating that the phenomenon is related to the final system created in the collision. In high-multiplicity events strangeness production reaches values similar to those observed in Pb-Pb collisions, where a QGP is formed.

Understanding the production mechanism of light (anti)nuclei is one of the key challenges of nuclear physics and has important consequences for astrophysics, since it provides an input for indirect dark-matter searches in space. In this paper, the latest results about the production of light (anti)nuclei in pp collisions at $\sqrt{s} = 13$ TeV are presented, focusing on the comparison with the predictions of coalescence and thermal models. For the first time, the coalescence parameters $B_2$ for deuterons and $B_3$ for helions are compared with parameter-free theoretical predictions that are directly constrained by the femtoscopic measurement of the source radius in the same event class. A fair description of the data with a Gaussian wave function is observed for both deuteron and helion, supporting the coalescence mechanism for the production of light (anti)nuclei in pp collisions. This method paves the way for future investigations of the internal structure of more complex nuclear clusters, including the hypertriton.

The study of the production of nuclei and antinuclei in pp collisions has proven to be a powerful tool to investigate the formation mechanism of loosely bound states in high-energy hadronic collisions. In this paper, the production of protons, deuterons and $^3$He and their charge conjugates at midrapidity is studied as a function of the charged-particle multiplicity in inelastic pp collisions at $\sqrt{s}=5.02$ TeV using the ALICE detector. Within the uncertainties, the yields of nuclei in pp collisions at $\sqrt{s}=5.02$ TeV are compatible with those in pp collisions at different energies and to those in p-Pb collisions when compared at similar multiplicities. The measurements are compared with the expectations of coalescence and Statistical Hadronisation Models. The results suggest a common formation mechanism behind the production of light nuclei in hadronic interactions and confirm that they do not depend on the collision energy but on the number of produced particles.

The multi-strange baryon yields in Pb--Pb collisions have been shown to exhibit an enhancement relative to pp reactions. In this work, $\Xi$ and $\Omega$ production rates have been measured with the ALICE experiment as a function of transverse momentum, ${p_{\rm T}}$, in p-Pb collisions at a centre-of-mass energy of ${\sqrt{s_{\rm NN}}}$ = 5.02 TeV. The results cover the kinematic ranges 0.6 GeV/$c<{p_{\rm T}} <$7.2 GeV/$c$ and 0.8 GeV/$c<{p_{\rm T}}<$ 5 GeV/$c$, for $\Xi$ and $\Omega$ respectively, in the common rapidity interval -0.5 $<{y_{\rm CMS}}<$ 0. Multi-strange baryons have been identified by reconstructing their weak decays into charged particles. The ${p_{\rm T}}$ spectra are analysed as a function of event charged-particle multiplicity, which in p-Pb collisions ranges over one order of magnitude and lies between those observed in pp and Pb-Pb collisions. The measured ${p_{\rm T}}$ distributions are compared to the expectations from a Blast-Wave model. The parameters which describe the production of lighter hadron species also describe the hyperon spectra in high multiplicity p-Pb. The yield of hyperons relative to charged pions is studied and compared with results from pp and Pb-Pb collisions. A statistical model is employed, which describes the change in the ratios with volume using a canonical suppression mechanism, in which the small volume causes a species-dependent relative reduction of hadron production. The calculations, in which the magnitude of the effect depends on the strangeness content, show good qualitative agreement with the data.

Direct photon production at mid-rapidity in Pb-Pb collisions at $\sqrt{s_{_{\mathrm{NN}}}} = 2.76$ TeV was studied in the transverse momentum range $0.9 < p_\mathrm{T} < 14$ GeV$/c$. Photons were detected with the highly segmented electromagnetic calorimeter PHOS and via conversions in the ALICE detector material with the $e^+e^-$ pair reconstructed in the central tracking system. The results of the two methods were combined and direct photon spectra were measured for the 0-20%, 20-40%, and 40-80% centrality classes. For all three classes, agreement was found with perturbative QCD calculations for $p_\mathrm{T} \gtrsim 5$ GeV$/c$. Direct photon spectra down to $p_\mathrm{T} \approx 1$ GeV$/c$ could be extracted for the 20-40% and 0-20% centrality classes. The significance of the direct photon signal for $0.9 < p_\mathrm{T} < 2.1$ GeV$/c$ is $2.6\sigma$ for the 0-20% class. The spectrum in this $p_\mathrm{T}$ range and centrality class can be described by an exponential with an inverse slope parameter of $(297 \pm 12^\mathrm{stat}\pm 41^\mathrm{syst})$ MeV. State-of-the-art models for photon production in heavy-ion collisions agree with the data within uncertainties.

The production of beauty hadrons was measured via semi-leptonic decays at mid-rapidity with the ALICE detector at the LHC in the transverse momentum interval $1<p_{\rm T}<8$ GeV/$c$ in minimum-bias p-Pb collisions at $\sqrt{s_{\rm NN}}=5.02$ TeV and in $1.3<p_{\rm T}<8$ GeV/$c$ in the 20% most central Pb-Pb collisions at $\sqrt{s_{\rm NN}}=2.76$ TeV. The pp reference spectra at $\sqrt{s}=5.02$ TeV and $\sqrt{s}=2.76$ TeV, needed for the calculation of the nuclear modification factors $R_{\rm pPb}$ and $R_{\rm PbPb}$, were obtained by a pQCD-driven scaling of the cross section of electrons from beauty-hadron decays measured at $\sqrt{s}=7$ TeV. In the $p_{\rm T}$ interval $3<p_{\rm T}<8$ GeV/$c$ a suppression of the yield of electrons from beauty-hadron decays is observed in Pb-Pb compared to pp collisions. Towards lower $p_{\rm T}$, the $R_{\rm PbPb}$ values increase with large systematic uncertainties. The $R_{\rm pPb}$ is consistent with unity within systematic uncertainties and is well described by theoretical calculations that include cold nuclear matter effects in p-Pb collisions. The measured $R_{\rm pPb}$ and these calculations indicate that cold nuclear matter effects are small at high transverse momentum also in Pb-Pb collisions. Therefore, the observed reduction of $R_{\rm PbPb}$ below unity at high $p_{\rm T}$ may be ascribed to an effect of the hot and dense medium formed in Pb-Pb collisions.

Comprehensive results on the production of unidentified charged particles, $\pi^{\pm}$, $\rm{K}^{\pm}$, $\rm{K}^{0}_{S}$, $\rm{K}$*(892)$^{0}$, $\rm{p}$, $\overline{\rm{p}}$, $\phi$(1020), $\Lambda$, $\overline{\Lambda}$, $\Xi^{-}$, $\overline{\Xi}^{+}$, $\Omega^{-}$ and $\overline{\Omega}^{+}$ hadrons in proton-proton (pp) collisions at $\sqrt{s}$ = 7 TeV at midrapidity ($|y| < 0.5$) as a function of charged-particle multiplicity density are presented. In order to avoid auto-correlation biases, the actual transverse momentum ($p_{\rm{T}}$) spectra of the particles under study and the event activity are measured in different rapidity windows. In the highest multiplicity class, the charged-particle density reaches about 3.5 times the value measured in inelastic collisions. While the yield of protons normalized to pions remains approximately constant as a function of multiplicity, the corresponding ratios of strange hadrons to pions show a significant enhancement that increases with increasing strangeness content. Furthermore, all identified particle to pion ratios are shown to depend solely on charged-particle multiplicity density, regardless of system type and collision energy. The evolution of the spectral shapes with multiplicity and hadron mass shows patterns that are similar to those observed in p-Pb and Pb-Pb collisions at LHC energies. The obtained $p_{\rm{T}}$ distributions and yields are compared to expectations from QCD-based pp event generators as well as to predictions from thermal and hydrodynamic models. These comparisons indicate that traces of a collective, equilibrated system are already present in high-multiplicity pp collisions.

The measurement of the production of deuterons, tritons and $^{3}\mathrm{He}$ and their antiparticles in Pb-Pb collisions at $\sqrt{s_{\mathrm{NN}}} = 5.02$ TeV is presented in this article. The measurements are carried out at midrapidity ($|y| < $ 0.5) as a function of collision centrality using the ALICE detector. The $p_{\rm T}$-integrated yields, the coalescence parameters and the ratios to protons and antiprotons are reported and compared with nucleosynthesis models. The comparison of these results in different collision systems at different centre-of-mass collision energies reveals a suppression of nucleus production in small systems. In the Statistical Hadronisation Model framework, this can be explained by a small correlation volume where the baryon number is conserved, as already shown in previous fluctuation analyses. However, a different size of the correlation volume is required to describe the proton yields in the same data sets. The coalescence model can describe this suppression by the fact that the wave functions of the nuclei are large and the fireball size starts to become comparable and even much smaller than the actual nucleus at low multiplicities.

This paper presents the measurements of $\pi^{\pm}$, $\rm{K}^{\pm}$, $\rm{p}$ and $\bar{\rm{p}}$ transverse momentum ($p_{\rm{T}}$) spectra as a function of charged-particle multiplicity density in proton-proton (pp) collisions at $\sqrt{s}$ = 13 TeV with the ALICE detector at the LHC. Such study allows us to isolate the center-of-mass energy dependence of light-flavour particle production. The measurements reported here cover a $p_{\rm{T}}$ range from 0.1 GeV/$c$ to 20 GeV/$c$ and are done in the rapidity interval $|y|<0.5$. The $p_{\rm{T}}$-differential particle ratios exhibit an evolution with multiplicity, similar to that observed in pp collisions at $\sqrt{s}$ = 7 TeV, which is qualitatively described by some of the hydrodynamical and pQCD-inspired models discussed in this paper. Furthermore, the $p_{\rm{T}}$-integrated hadron-to-pion yield ratios measured in pp collisions at two different center-of-mass energies are consistent when compared at similar multiplicities. This also extends to strange and multistrange hadrons, suggesting that, at LHC energies, particle hadrochemistry scales with particle multiplicity the same way under different collision energies and colliding systems.