We report the first measurement of the net-charge fluctuations in Pb-Pb collisions at $\sqrt{s_{\rm NN}}$ = 2.76 TeV, measured with the ALICE detector at the CERN Large Hadron Collider. The dynamical fluctuations per unit entropy are observed to decrease when going from peripheral to central collisions. An additional reduction in the amount of fluctuations is seen in comparison to the results from lower energies. We examine the dependence of fluctuations on the pseudorapidity interval, which may account for the dilution of fluctuations during the evolution of the system. We find that the fluctuations at LHC are smaller compared to the measurements at the Relativistic heavy Ion Collider (RHIC), and as such, closer to what has been theoretically predicted for the formation of Quark-Gluon Plasma (QGP).

The first evidence of spin alignment of vector mesons ($K^{*0}$ and $\phi$) in heavy-ion collisions at the Large Hadron Collider (LHC) is reported. The spin density matrix element $\rho_{00}$ is measured at midrapidity ($|y| <$ 0.5) in Pb-Pb collisions at a center-of-mass energy ($\sqrt{s_{\rm NN}}$) of 2.76 TeV with the ALICE detector. $\rho_{00}$ values are found to be less than 1/3 (1/3 implies no spin alignment) at low transverse momentum ($p_{\rm T} <$ 2 GeV/$c$) for $K^{*0}$ and $\phi$ at a level of 3$\sigma$ and 2$\sigma$, respectively. No significant spin alignment is observed for the $K^0_S$ meson (spin = 0) in Pb-Pb collisions and for the vector mesons in $pp$ collisions. The measured spin alignment is unexpectedly large but qualitatively consistent with the expectation from models which attribute it to a polarization of quarks in the presence of angular momentum in heavy-ion collisions and a subsequent hadronization by the process of recombination.

The first study of $\phi$-meson production in p-Pb collisions at forward and backward rapidity, at a nucleon-nucleon centre-of-mass energy $\sqrt{s_{\rm NN}} = 5.02$~TeV, has been performed with the ALICE apparatus at the LHC. The $\phi$-mesons have been identified in the dimuon decay channel in the transverse momentum ($p_{\rm T}$) range $1 < p_{\rm T} < 7$ GeV/$c$, both in the p-going ($2.03 < y < 3.53$) and the Pb-going ($-4.46 < y < -2.96$) directions, where $y$ stands for the rapidity in the nucleon-nucleon centre-of-mass, the integrated luminosity amounting to $5.01 \pm 0.19$~nb$^{-1}$ and $5.81 \pm 0.20$~nb$^{-1}$, respectively, for the two data samples. Differential cross sections as a function of transverse momentum and rapidity are presented. The forward-backward ratio for $\phi$-meson production is measured for $2.96<|y|<3.53$, resulting in a ratio $\sim 0.5$ with no significant $p_{\rm T}$ dependence within the uncertainties. The $p_{\rm T}$ dependence of the $\phi$ nuclear modification factor $R_{\rm pPb}$ exhibits an enhancement up to a factor 1.6 at $p_{\rm T}$ = 3-4 GeV/$c$ in the Pb-going direction. The $p_{\rm T}$ dependence of the $\phi$-meson cross section in pp collisions at $\sqrt{s}$ = 2.76 TeV, which is used to determine a reference for the p-Pb results, is also presented here for $1 < p_{\rm T} < 5$ GeV/$c$ and $2.5 <y < 4$ for a $78 \pm 3$~nb$^{-1}$ integrated luminosity sample.

We present the measurements of particle pair yields per trigger particle obtained from di-hadron azimuthal correlations in pp collisions at $\sqrt{s} = 0.9$, $2.76$, and $7$ TeV recorded with the ALICE detector. The yields are studied as a function of the charged particle multiplicity. Taken together with the single particle yields the pair yields provide information about parton fragmentation at low transverse momenta, as well as on the contribution of multiple parton interactions to particle production. Data are compared to calculations using the PYTHIA6, PYTHIA8, and PHOJET event generators.

This publication describes the methods used to measure the centrality of inelastic Pb-Pb collisions at a center-of-mass energy of 2.76 TeV per colliding nucleon pair with ALICE. The centrality is a key parameter in the study of the properties of QCD matter at extreme temperature and energy density, because it is directly related to the initial overlap region of the colliding nuclei. Geometrical properties of the collision, such as the number of participating nucleons and number of binary nucleon-nucleon collisions, are deduced from a Glauber model with a sharp impact parameter selection, and shown to be consistent with those extracted from the data. The centrality determination provides a tool to compare ALICE measurements with those of other experiments and with theoretical calculations.

We present the results of three-dimensional femtoscopic analyses for charged and neutral kaons recorded by ALICE in Pb-Pb collisions at $\sqrt{s_{\rm{NN}}}$ = 2.76 TeV. Femtoscopy is used to measure the space-time characteristics of particle production from the effects of quantum statistics and final-state interactions in two-particle correlations. Kaon femtoscopy is an important supplement to that of pions because it allows one to distinguish between different model scenarios working equally well for pions. In particular, we compare the measured 3D kaon radii with a purely hydrodynamical calculation and a model where the hydrodynamic phase is followed by a hadronic rescattering stage. The former predicts an approximate transverse mass ($m_{\mathrm{T}}$) scaling of source radii obtained from pion and kaon correlations. This $m_{\mathrm{T}}$ scaling appears to be broken in our data, which indicates the importance of the hadronic rescattering phase at LHC energies. A $k_{\mathrm{T}}$ scaling of pion and kaon source radii is observed instead. The time of maximal emission of the system is estimated using the three-dimensional femtoscopic analysis for kaons. The measured emission time is larger than that of pions. Our observation is well supported by the hydrokinetic model predictions.

The ALICE measurement of K$^0_{\rm S}$ and $\rm\Lambda$ production at mid-rapidity in Pb-Pb collisions at $\sqrt{s_{\rm NN}} = 2.76$ TeV is presented. The transverse momentum ($p_{\rm T}$) spectra are shown for several collision centrality intervals and in the $p_{\rm T}$ range from 0.4 GeV/$c$ (0.6 GeV/$c$ for $\rm\Lambda$) to 12 GeV/$c$. The $p_{\rm T}$ dependence of the $\rm \Lambda$/K$^0_{\rm S}$ ratios exhibits maxima in the vicinity of 3 GeV/$c$, and the positions of the maxima shift towards higher $p_{\rm T}$ with increasing collision centrality. The magnitude of these maxima increases by almost a factor of three between most peripheral and most central Pb-Pb collisions. This baryon excess at intermediate $p_{\rm T}$ is not observed in pp interactions at sqrt(s) = 0.9 TeV and at sqrt(s) = 7 TeV. Qualitatively, the baryon enhancement in heavy-ion collisions is expected from radial flow. However, the measured $p_{\rm T}$ spectra above 2 GeV/$c$ progressively decouple from hydrodynamical-model calculations. For higher values of $p_{\rm T}$, models that incorporate the influence of the medium on the fragmentation and hadronization processes describe qualitatively the $p_{\rm T}$ dependence of the $\rm\Lambda$/K$^0_{\rm S}$ ratio.

Direct photon production at mid-rapidity in Pb-Pb collisions at $\sqrt{s_{_{\mathrm{NN}}}} = 2.76$ TeV was studied in the transverse momentum range $0.9 < p_\mathrm{T} < 14$ GeV$/c$. Photons were detected with the highly segmented electromagnetic calorimeter PHOS and via conversions in the ALICE detector material with the $e^+e^-$ pair reconstructed in the central tracking system. The results of the two methods were combined and direct photon spectra were measured for the 0-20%, 20-40%, and 40-80% centrality classes. For all three classes, agreement was found with perturbative QCD calculations for $p_\mathrm{T} \gtrsim 5$ GeV$/c$. Direct photon spectra down to $p_\mathrm{T} \approx 1$ GeV$/c$ could be extracted for the 20-40% and 0-20% centrality classes. The significance of the direct photon signal for $0.9 < p_\mathrm{T} < 2.1$ GeV$/c$ is $2.6\sigma$ for the 0-20% class. The spectrum in this $p_\mathrm{T}$ range and centrality class can be described by an exponential with an inverse slope parameter of $(297 \pm 12^\mathrm{stat}\pm 41^\mathrm{syst})$ MeV. State-of-the-art models for photon production in heavy-ion collisions agree with the data within uncertainties.

Measurements of multi-particle azimuthal correlations (cumulants) for charged particles in p-Pb and Pb-Pb collisions are presented. They help address the question of whether there is evidence for global, flow-like, azimuthal correlations in the p-Pb system. Comparisons are made to measurements from the larger Pb-Pb system, where such evidence is established. In particular, the second harmonic two-particle cumulants are found to decrease with multiplicity, characteristic of a dominance of few-particle correlations in p-Pb collisions. However, when a $|\Delta \eta|$ gap is placed to suppress such correlations, the two-particle cumulants begin to rise at high-multiplicity, indicating the presence of global azimuthal correlations. The Pb-Pb values are higher than the p-Pb values at similar multiplicities. In both systems, the second harmonic four-particle cumulants exhibit a transition from positive to negative values when the multiplicity increases. The negative values allow for a measurement of $v_{2}\{4\}$ to be made, which is found to be higher in Pb-Pb collisions at similar multiplicities. The second harmonic six-particle cumulants are also found to be higher in Pb-Pb collisions. In Pb-Pb collisions, we generally find $v_{2}\{4\} \simeq v_{2}\{6\}\neq 0$ which is indicative of a Bessel-Gaussian function for the $v_{2}$ distribution. For very high-multiplicity Pb-Pb collisions, we observe that the four- and six-particle cumulants become consistent with 0. Finally, third harmonic two-particle cumulants in p-Pb and Pb-Pb are measured. These are found to be similar for overlapping multiplicities, when a $|\Delta\eta| > 1.4$ gap is placed.

A detailed study of pseudorapidity densities and multiplicity distributions of primary charged particles produced in proton-proton collisions, at $\sqrt{s} =$ 0.9, 2.36, 2.76, 7 and 8 TeV, in the pseudorapidity range $|\eta|<2$, was carried out using the ALICE detector. Measurements were obtained for three event classes: inelastic, non-single diffractive and events with at least one charged particle in the pseudorapidity interval $|\eta|<1$. The use of an improved track-counting algorithm combined with ALICE's measurements of diffractive processes allows a higher precision compared to our previous publications. A KNO scaling study was performed in the pseudorapidity intervals $|\eta|<$ 0.5, 1.0 and 1.5. The data are compared to other experimental results and to models as implemented in Monte Carlo event generators PHOJET and recent tunes of PYTHIA6, PYTHIA8 and EPOS.