This publication describes the methods used to measure the centrality of inelastic Pb-Pb collisions at a center-of-mass energy of 2.76 TeV per colliding nucleon pair with ALICE. The centrality is a key parameter in the study of the properties of QCD matter at extreme temperature and energy density, because it is directly related to the initial overlap region of the colliding nuclei. Geometrical properties of the collision, such as the number of participating nucleons and number of binary nucleon-nucleon collisions, are deduced from a Glauber model with a sharp impact parameter selection, and shown to be consistent with those extracted from the data. The centrality determination provides a tool to compare ALICE measurements with those of other experiments and with theoretical calculations.

Measurements of charged pion and kaon production in central Pb+Pb collisions at 40, 80 and 158 AGeV are presented. These are compared with data at lower and higher energies as well as with results from p+p interactions. The mean pion multiplicity per wounded nucleon increases approximately linearly with s_NN^1/4 with a change of slope starting in the region 15-40 AGeV. The change from pion suppression with respect to p+p interactions, as observed at low collision energies, to pion enhancement at high energies occurs at about 40 AGeV. A non-monotonic energy dependence of the ratio of K^+ to pi^+ yields is observed, with a maximum close to 40 AGeV and an indication of a nearly constant value at higher energies.The measured dependences may be related to an increase of the entropy production and a decrease of the strangeness to entropy ratio in central Pb+Pb collisions in the low SPS energy range, which is consistent with the hypothesis that a transient state of deconfined matter is created above these energies. Other interpretations of the data are also discussed.

The pseudorapidity density of charged particles, $\rm{d}\it{N}_\rm{ch}/\rm{d}\it{\eta}$, in p-Pb collisions has been measured at a centre-of-mass energy per nucleon-nucleon pair of $\sqrt{s_{\rm{NN}}}$ = 8.16 TeV at mid-pseudorapidity for non-single-diffractive events. The results cover 3.6 units of pseudorapidity, $|\eta|<1.8$. The $\rm{d}\it{N}_\rm{ch}/\rm{d}\it{\eta}$ value is $19.1\pm0.7$ at $|\eta|<0.5$. This quantity divided by $\langle N_\rm{part} \rangle/2$, is $4.73\pm0.20$, which is 9.5% higher than the corresponding value for p-Pb collisions at $\sqrt{s_{\rm{NN}}}$ = 5.02 TeV. Measurements are compared with models based on different mechanisms for particle production. All models agree within uncertainties with data in the Pb-going side, while HIJING overestimates, showing a symmetric behaviour, and EPOS underestimates the p-going side of the $\rm{d}\it{N}_\rm{ch}/\rm{d}\it{\eta}$ distribution. Saturation-based models reproduce the distributions well for $\eta>-1.3$. The $\rm{d}\it{N}_\rm{ch}/\rm{d}\it{\eta}$ is also measured for different centrality estimators, based both on the charged-particle multiplicity and on the energy deposited in the Zero-Degree Calorimeters. A study of the implications of the large multiplicity fluctuations due to the small number of participants for systems like p-Pb in the centrality calculation for multiplicity-based estimators is discussed, demonstrating the advantages of determining the centrality with energy deposited near beam rapidity.

The production of Λ,\(\bar \Lambda\) andKs0 has been studied in 200 GeV/nucleonp+S and S+S collisions in the streamer chamber of the NA35 experiment at the CERN SPS. Significant enhancement of the multiplicities of all observed strange particles relative to negative hadrons was observed in central S+S collisions, as compared top+p andp+S collisions. The latter collisions show no overall (relative) strangeness enhancement overp+p, but the rapidity distributions and hadron multiplicities indicate some secondary cascading production of Λ particles in thep+S andp+Au collisions. The Λ polarization in central S+S collisions was found to be compatible with zero up topT=2 GeV/c.

Data on multiplicities of charged particles produced in proton-nucleus and nucleus-nucleus collisions at 200 GeV per nucleon are presented. It is shown that the mean multiplicity of negative particles is proportional to the mean number of nucleons participating in the collision both for nucleus-nucleus and proton-nucleus collisions. The apparent consistency of pion multiplicity data with the assumption of an incoherent superposition of nucleon-nucleon collisions is critically discussed.

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We present the first wide-range measurement of the charged-particle pseudorapidity density distribution, for different centralities (the 0-5%, 5-10%, 10-20%, and 20-30% most central events) in Pb-Pb collisions at $\sqrt{s_{\rm NN}} = 2.76$ TeV at the LHC. The measurement is performed using the full coverage of the ALICE detectors, $-5.0 < \eta < 5.5$, and employing a special analysis technique based on collisions arising from LHC "satellite" bunches. We present the pseudorapidity density as a function of the number of participating nucleons as well as an extrapolation to the total number of produced charged particles ($N_{\rm ch} = 17165 \pm 772$ for the 0-5% most central collisions). From the measured ${\rm d}N_{\rm ch}/{\rm d}\eta$ distribution we derive the rapidity density distribution, ${\rm d}N_{\rm ch}/{\rm d}y$, under simple assumptions. The rapidity density distribution is found to be significantly wider than the predictions of the Landau model. We assess the validity of longitudinal scaling by comparing to lower energy results from RHIC. Finally the mechanisms of the underlying particle production are discussed based on a comparison with various theoretical models.

Inelastic cross sections at 60 and 200 GeV/nucleon are determined in a streamer chamber for 16 O on several nuclear targets. Charged particle multiplicity distributions for inelastic and central collisions are studied and compared with theoretical predictions. The inelastic cross section exhibit a geometrical dependence on nuclear radii. The multiplicity data are governed by the collision geometry. They are consistent with a picture of superposition of independent nucleon-nucleus interactions.

Multiplicity distributions of negatively charged particles have been studied in restricted phase space intervals for central S+S, O+Au and S+Au collisions at 200 GeV/nucleon. It is shown that multiplicity distributions are well described by a negative binomial form irrespectively of the size and dimensionality of phase space domain. A clan structure analysis reveals interesting similarities between complex nuclear collisions and a simple partonic shower. The lognormal distribution agrees reasonably well with the multiplicity data in large domains, but fails in the case of small intervals. No universal scaling function was found to describe the shape of multiplicity distributions in phase space intervals of varying size.

Results on charged pion and kaon production in central Pb+Pb collisions at 20A and 30A GeV are presented and compared to data at lower and higher energies. A rapid change of the energy dependence is observed around 30A GeV for the yields of pions and kaons as well as for the shape of the transverse mass spectra. The change is compatible with the prediction that the threshold for production of a state of deconfined matter at the early stage of the collisions is located at low SPS energies.