The pseudorapidity density and multiplicity distribution of charged particles produced in proton-proton collisions at the LHC, at a centre-of-mass energy $\sqrt{s} = 7$ TeV, were measured in the central pseudorapidity region |$\eta$| < 1. Comparisons are made with previous measurements at $\sqrt{s}$ = 0.9 TeV and 2.36 TeV. At $\sqrt{s}$ = 7 TeV, for events with at least one charged particle in |$\eta$| < 1, we obtain dNch/deta = 6.01 $\pm$ 0.01 (stat.) $^{+0.20}_{-0.12}$ (syst.). This corresponds to an increase of 57.6% $\pm$ 0.4% (stat.) $^{+3.6}_{-1.8}$% (syst.) relative to collisions at 0.9 TeV, significantly higher than calculations from commonly used models. The multiplicity distribution at 7 TeV is described fairly well by the negative binomial distribution.
A detailed study of pseudorapidity densities and multiplicity distributions of primary charged particles produced in proton-proton collisions, at $\sqrt{s} =$ 0.9, 2.36, 2.76, 7 and 8 TeV, in the pseudorapidity range $|\eta|<2$, was carried out using the ALICE detector. Measurements were obtained for three event classes: inelastic, non-single diffractive and events with at least one charged particle in the pseudorapidity interval $|\eta|<1$. The use of an improved track-counting algorithm combined with ALICE's measurements of diffractive processes allows a higher precision compared to our previous publications. A KNO scaling study was performed in the pseudorapidity intervals $|\eta|<$ 0.5, 1.0 and 1.5. The data are compared to other experimental results and to models as implemented in Monte Carlo event generators PHOJET and recent tunes of PYTHIA6, PYTHIA8 and EPOS.
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