The first measurement of two-pion Bose-Einstein correlations in central Pb-Pb collisions at $\sqrt{s_{\rm NN}} = 2.76$ TeV at the Large Hadron Collider is presented. We observe a growing trend with energy now not only for the longitudinal and the outward but also for the sideward pion source radius. The pion homogeneity volume and the decoupling time are significantly larger than those measured at RHIC.

The pseudorapidity density and multiplicity distribution of charged particles produced in proton-proton collisions at the LHC, at a centre-of-mass energy $\sqrt{s} = 7$ TeV, were measured in the central pseudorapidity region |$\eta$| < 1. Comparisons are made with previous measurements at $\sqrt{s}$ = 0.9 TeV and 2.36 TeV. At $\sqrt{s}$ = 7 TeV, for events with at least one charged particle in |$\eta$| < 1, we obtain dNch/deta = 6.01 $\pm$ 0.01 (stat.) $^{+0.20}_{-0.12}$ (syst.). This corresponds to an increase of 57.6% $\pm$ 0.4% (stat.) $^{+3.6}_{-1.8}$% (syst.) relative to collisions at 0.9 TeV, significantly higher than calculations from commonly used models. The multiplicity distribution at 7 TeV is described fairly well by the negative binomial distribution.

Charged-particle production was studied in proton-proton collisions collected at the LHC with the ALICE detector at centre-of-mass energies 0.9 TeV and 2.36 TeV in the pseudorapidity range |$\eta$| < 1.4. In the central region (|$\eta$| < 0.5), at 0.9 TeV, we measure charged-particle pseudorapidity density dNch/deta = 3.02 $\pm$ 0.01 (stat.) $^{+0.08}_{-0.05}$ (syst.) for inelastic interactions, and dNch/deta = 3.58 $\pm$ 0.01 (stat.) $^{+0.12}_{-0.12}$ (syst.) for non-single-diffractive interactions. At 2.36 TeV, we find dNch/deta = 3.77 $\pm$ 0.01 (stat.) $^{+0.25}_{-0.12}$ (syst.) for inelastic, and dNch/deta = 4.43 $\pm$ 0.01 (stat.) $^{+0.17}_{-0.12}$ (syst.) for non-single-diffractive collisions. The relative increase in charged-particle multiplicity from the lower to higher energy is 24.7% $\pm$ 0.5% (stat.) $^{+5.7}_{-2.8}$% (syst.) for inelastic and 23.7% $\pm$ 0.5% (stat.) $^{+4.6}_{-1.1}$% (syst.) for non-single-diffractive interactions. This increase is consistent with that reported by the CMS collaboration for non-single-diffractive events and larger than that found by a number of commonly used models. The multiplicity distribution was measured in different pseudorapidity intervals and studied in terms of KNO variables at both energies. The results are compared to proton-antiproton data and to model predictions.

The ratio of the yields of antiprotons to protons in pp collisions has been measured by the ALICE experiment at $\sqrt{s} = 0.9$ and $7$ TeV during the initial running periods of the Large Hadron Collider(LHC). The measurement covers the transverse momentum interval $0.45 < p_{\rm{t}} < 1.05$ GeV/$c$ and rapidity $|y| < 0.5$. The ratio is measured to be $R_{|y| < 0.5} = 0.957 \pm 0.006 (stat.) \pm 0.014 (syst.)$ at $0.9$ TeV and $R_{|y| < 0.5} = 0.991 \pm 0.005 (stat.) \pm 0.014 (syst.)$ at $7$ TeV and it is independent of both rapidity and transverse momentum. The results are consistent with the conventional model of baryon-number transport and set stringent limits on any additional contributions to baryon-number transfer over very large rapidity intervals in pp collisions.

A detailed study of pseudorapidity densities and multiplicity distributions of primary charged particles produced in proton-proton collisions, at $\sqrt{s} =$ 0.9, 2.36, 2.76, 7 and 8 TeV, in the pseudorapidity range $|\eta|<2$, was carried out using the ALICE detector. Measurements were obtained for three event classes: inelastic, non-single diffractive and events with at least one charged particle in the pseudorapidity interval $|\eta|<1$. The use of an improved track-counting algorithm combined with ALICE's measurements of diffractive processes allows a higher precision compared to our previous publications. A KNO scaling study was performed in the pseudorapidity intervals $|\eta|<$ 0.5, 1.0 and 1.5. The data are compared to other experimental results and to models as implemented in Monte Carlo event generators PHOJET and recent tunes of PYTHIA6, PYTHIA8 and EPOS.

The global polarization of the $\Lambda$ and $\overline\Lambda$ hyperons is measured for Pb-Pb collisions at $\sqrt{s_{\rm{NN}}}$ = 2.76 and 5.02 TeV recorded with the ALICE at the LHC. The results are reported differentially as a function of collision centrality and hyperon's transverse momentum ($p_{\rm{T}}$) for the range of centrality 5-50%, $0.5 < p_{\rm{T}} <5$ GeV/$c$, and rapidity $|y|<0.5$. The hyperon global polarization averaged for Pb-Pb collisions at $\sqrt{s_{\rm{NN}}}$ = 2.76 and 5.02 TeV is found to be consistent with zero, $\langle P_{\rm{H}}\rangle$ (%) $\approx$ - 0.01 $\pm$ 0.05 (stat.) $\pm$ 0.03 (syst.) in the collision centrality range 15-50%, where the largest signal is expected. The results are compatible with expectations based on an extrapolation from measurements at lower collision energies at RHIC, hydrodynamical model calculations, and empirical estimates based on collision energy dependence of directed flow, all of which predict the global polarization values at LHC energies of the order of 0.01%.

We report the first results of elliptic ($v_2$), triangular ($v_3$) and quadrangular flow ($v_4$) of charged particles in Pb-Pb collisions at $\sqrt{s_{\rm NN}}=5.02$ TeV with the ALICE detector at the CERN Large Hadron Collider. The measurements are performed in the central pseudorapidity region $|\eta|<0.8$ and for the transverse momentum range $0.2<p_{\rm T}<5$ GeV/$c$. The anisotropic flow is measured using two-particle correlations with a pseudorapidity gap greater than one unit and with the multi-particle cumulant method. Compared to results from Pb-Pb collisions at $\sqrt{s_{\rm NN}}=2.76$ TeV, the anisotropic flow coefficients $v_{2}$, $v_{3}$ and $v_{4}$ are found to increase by ($3.0\pm0.6$)%, ($4.3\pm1.4$)% and ($10.2\pm3.8$)%, respectively, in the centrality range 0-50%. This increase can be attributed mostly to an increase of the average transverse momentum between the two energies. The measurements are found to be compatible with hydrodynamic model calculations. This comparison provides a unique opportunity to test the validity of the hydrodynamic picture and the power to further discriminate between various possibilities for the temperature dependence of shear viscosity to entropy density ratio of the produced matter in heavy-ion collisions at the highest energies.

The production of $\pi^{\pm}$, $\rm{K}^{\pm}$, $\rm{K}^{0}_{S}$, $\rm{K}^{*}(892)^{0}$, $\rm{p}$, $\phi(1020)$, $\Lambda$, $\Xi^{-}$, $\Omega^{-}$, and their antiparticles was measured in inelastic proton-proton (pp) collisions at a center-of-mass energy of $\sqrt{s}$ = 13 TeV at midrapidity ($|y|<0.5$) as a function of transverse momentum ($p_{\rm{T}}$) using the ALICE detector at the CERN LHC. Furthermore, the single-particle $p_{\rm{T}}$ distributions of $\rm{K}^{0}_{S}$, $\Lambda$, and $\overline{\Lambda}$ in inelastic pp collisions at $\sqrt{s}$ = 7 TeV are reported here for the first time. The $p_{\rm{T}}$ distributions are studied at midrapidity within the transverse momentum range $0\leq p_{\rm{T}}\leq20$ GeV/$c$, depending on the particle species. The $p_{\rm{T}}$ spectra, integrated yields, and particle yield ratios are discussed as a function of collision energy and compared with measurements at lower $\sqrt{s}$ and with results from various general-purpose QCD-inspired Monte Carlo models. A hardening of the spectra at high $p_{\rm{T}}$ with increasing collision energy is observed, which is similar for all particle species under study. The transverse mass and $x_{\rm{T}}\equiv2p_{\rm{T}}/\sqrt{s}$ scaling properties of hadron production are also studied. As the collision energy increases from $\sqrt{s}$ = 7 to 13 TeV, the yields of non- and single-strange hadrons normalized to the pion yields remain approximately constant as a function of $\sqrt{s}$, while ratios for multi-strange hadrons indicate enhancements. The $p_{\rm{T}}$-differential cross sections of $\pi^{\pm}$, $\rm{K}^{\pm}$ and $\rm{p}$ ($\overline{\rm{p}}$) are compared with next-to-leading order perturbative QCD calculations, which are found to overestimate the cross sections for $\pi^{\pm}$ and $\rm{p}$ ($\overline{\rm{p}}$) at high $p_{\rm{T}}$.

The multiplicity and pseudorapidity distributions of inclusive photons have been measured at forward rapidities ($2.3 < \eta < 3.9$) in proton-proton collisions at three center-of-mass energies, $\sqrt{s}=0.9$, 2.76 and 7 TeV using the ALICE detector. It is observed that the increase in the average photon multiplicity as a function of beam energy is compatible with both a logarithmic and a power-law dependence. The relative increase in average photon multiplicity produced in inelastic pp collisions at 2.76 and 7 TeV center-of-mass energies with respect to 0.9 TeV are 37.2% $\pm$ 0.3% (stat) $\pm$ 8.8% (sys) and 61.2% $\pm$ 0.3% (stat) $\pm$ 7.6% (sys), respectively. The photon multiplicity distributions for all center-of-mass energies are well described by negative binomial distributions. The multiplicity distributions are also presented in terms of KNO variables. The results are compared to model predictions, which are found in general to underestimate the data at large photon multiplicities, in particular at the highest center-of-mass energy. Limiting fragmentation behavior of photons has been explored with the data, but is not observed in the measured pseudorapidity range.

Differential cross sections of charged particles in inelastic pp collisions as a function of $p_{\rm T}$ have been measured at $\sqrt{s}=$ 0.9, 2.76 and 7 TeV at the LHC. The $p_{\rm T}$ spectra are compared to NLO-pQCD calculations. Though the differential cross section for an individual $\sqrt{s}$ cannot be described by NLO-pQCD, the relative increase of cross section with $\sqrt{s}$ is in agreement with NLO-pQCD. Based on these measurements and observations, procedures are discussed to construct pp reference spectra at $\sqrt{s} =$ 2.76 and 5.02 TeV up to $p_{\rm T}$ = 50 GeV/$c$ as required for the calculation of the nuclear modification factor in nucleus-nucleus and proton-nucleus collisions.