The production of $\pi^{\pm}$, $\rm{K}^{\pm}$, $\rm{K}^{0}_{S}$, $\rm{K}^{*}(892)^{0}$, $\rm{p}$, $\phi(1020)$, $\Lambda$, $\Xi^{-}$, $\Omega^{-}$, and their antiparticles was measured in inelastic proton-proton (pp) collisions at a center-of-mass energy of $\sqrt{s}$ = 13 TeV at midrapidity ($|y|<0.5$) as a function of transverse momentum ($p_{\rm{T}}$) using the ALICE detector at the CERN LHC. Furthermore, the single-particle $p_{\rm{T}}$ distributions of $\rm{K}^{0}_{S}$, $\Lambda$, and $\overline{\Lambda}$ in inelastic pp collisions at $\sqrt{s}$ = 7 TeV are reported here for the first time. The $p_{\rm{T}}$ distributions are studied at midrapidity within the transverse momentum range $0\leq p_{\rm{T}}\leq20$ GeV/$c$, depending on the particle species. The $p_{\rm{T}}$ spectra, integrated yields, and particle yield ratios are discussed as a function of collision energy and compared with measurements at lower $\sqrt{s}$ and with results from various general-purpose QCD-inspired Monte Carlo models. A hardening of the spectra at high $p_{\rm{T}}$ with increasing collision energy is observed, which is similar for all particle species under study. The transverse mass and $x_{\rm{T}}\equiv2p_{\rm{T}}/\sqrt{s}$ scaling properties of hadron production are also studied. As the collision energy increases from $\sqrt{s}$ = 7 to 13 TeV, the yields of non- and single-strange hadrons normalized to the pion yields remain approximately constant as a function of $\sqrt{s}$, while ratios for multi-strange hadrons indicate enhancements. The $p_{\rm{T}}$-differential cross sections of $\pi^{\pm}$, $\rm{K}^{\pm}$ and $\rm{p}$ ($\overline{\rm{p}}$) are compared with next-to-leading order perturbative QCD calculations, which are found to overestimate the cross sections for $\pi^{\pm}$ and $\rm{p}$ ($\overline{\rm{p}}$) at high $p_{\rm{T}}$.

The transverse structure of jets was studied via jet fragmentation transverse momentum ($j_{\rm{T}}$) distributions, obtained using two-particle correlations in proton-proton and proton-lead collisions, measured with the ALICE experiment at the LHC. The highest transverse momentum particle in each event is used as the trigger particle and the region $3 < p_{\rm{Tt}} < 15$ GeV/$c$ is explored in this study. The measured distributions show a clear narrow Gaussian component and a wide non-Gaussian one. Based on Pythia simulations, the narrow component can be related to non-perturbative hadronization and the wide component to quantum chromodynamical splitting. The width of the narrow component shows a weak dependence on the transverse momentum of the trigger particle, in agreement with the expectation of universality of the hadronization process. On the other hand, the width of the wide component shows a rising trend suggesting increased branching for higher transverse momentum. The results obtained in pp collisions at $\sqrt{s}$ = 7 TeV and in p-Pb collisions at $\sqrt{s_{\rm{NN}}}$ = 5.02 TeV are compatible within uncertainties and hence no significant cold nuclear matter effects are observed. The results are compared to previous measurements from CCOR and PHENIX as well as to Pythia 8 and Herwig 7 simulations.

The production of J/$\psi$ is measured as a function of charged-particle multiplicity at forward rapidity in proton$-$proton (pp) collisions at center-of-mass energies $\sqrt{s} =$ 5.02 and 13 TeV. The J/$\psi$ mesons are reconstructed via their decay into dimuons in the rapidity interval (2.5 $< y <$ 4.0), whereas the charged-particle multiplicity density (${\rm d}N_{\rm{ch}}/{\rm d}\eta$) is measured at midrapidity $(|\eta| < 1)$. The production rate as a function of multiplicity is reported as the ratio of the yield in a given multiplicity interval to the multiplicity-integrated one. This observable shows a linear increase with charged-particle multiplicity normalized to the corresponding average value for inelastic events (${{\rm d}N_{\rm ch}/{\rm d}\eta}/{\langle {\rm d}N_{\rm ch}/{\rm d}\eta \rangle}$), at both the colliding energies. Measurements are compared with available ALICE results at midrapidity and theoretical model calculations. First measurement of the mean transverse momentum ($\langle p_{\mathrm{T}}\rangle$) of J/$\psi$ in pp collisions exhibits an increasing trend as a function of ${{\rm d}N_{\rm ch}/{\rm d}\eta}/{\langle {\rm d}N_{\rm ch}/{\rm d}\eta \rangle}$ showing a saturation towards high charged-particle multiplicities.

Differential cross sections of charged particles in inelastic pp collisions as a function of $p_{\rm T}$ have been measured at $\sqrt{s}=$ 0.9, 2.76 and 7 TeV at the LHC. The $p_{\rm T}$ spectra are compared to NLO-pQCD calculations. Though the differential cross section for an individual $\sqrt{s}$ cannot be described by NLO-pQCD, the relative increase of cross section with $\sqrt{s}$ is in agreement with NLO-pQCD. Based on these measurements and observations, procedures are discussed to construct pp reference spectra at $\sqrt{s} =$ 2.76 and 5.02 TeV up to $p_{\rm T}$ = 50 GeV/$c$ as required for the calculation of the nuclear modification factor in nucleus-nucleus and proton-nucleus collisions.

The multiplicity and pseudorapidity distributions of inclusive photons have been measured at forward rapidities ($2.3 < \eta < 3.9$) in proton-proton collisions at three center-of-mass energies, $\sqrt{s}=0.9$, 2.76 and 7 TeV using the ALICE detector. It is observed that the increase in the average photon multiplicity as a function of beam energy is compatible with both a logarithmic and a power-law dependence. The relative increase in average photon multiplicity produced in inelastic pp collisions at 2.76 and 7 TeV center-of-mass energies with respect to 0.9 TeV are 37.2% $\pm$ 0.3% (stat) $\pm$ 8.8% (sys) and 61.2% $\pm$ 0.3% (stat) $\pm$ 7.6% (sys), respectively. The photon multiplicity distributions for all center-of-mass energies are well described by negative binomial distributions. The multiplicity distributions are also presented in terms of KNO variables. The results are compared to model predictions, which are found in general to underestimate the data at large photon multiplicities, in particular at the highest center-of-mass energy. Limiting fragmentation behavior of photons has been explored with the data, but is not observed in the measured pseudorapidity range.

The measurements of the production of prompt ${\rm D^0}$, ${\rm D^+}$, ${\rm D^{*+}}$, and ${{\rm D^+_s}}$ mesons in proton--proton (pp) collisions at $\sqrt{s}=5.02$ TeV with the ALICE detector at the Large Hadron Collider (LHC) are reported. D mesons were reconstructed at mid-rapidity ($|y|<0.5$) via their hadronic decay channels ${\rm D}^0 \to {\rm K}^-\pi^+$, ${\rm D}^+\to {\rm K}^-\pi^+\pi^+$, ${\rm D}^{*+} \to {\rm D}^0 \pi^+ \to {\rm K}^- \pi^+ \pi^+$, ${\rm D^{+}_{s}\to \phi\pi^+\to K^{+} K^{-} \pi^{+}}$, and their charge conjugates. The production cross sections were measured in the transverse momentum interval $0<p_{\rm T}<36~\mathrm{GeV}/c$ for ${\rm D^0}$, $1<p_{\rm T}<36~\mathrm{GeV}/c$ for ${\rm D^+}$ and ${\rm D^{*+}}$, and in $2<p_{\rm T}<24~\mathrm{GeV}/c$ for ${{\rm D^+_s}}$ mesons. Thanks to the higher integrated luminosity, an analysis in finer $p_{\rm T}$ bins with respect to the previous measurements at $\sqrt{s}=7$ TeV was performed, allowing for a more detailed description of the cross-section $p_{\rm T}$ shape. The measured $p_{\rm T}$-differential production cross sections are compared to the results at $\sqrt{s}=7$ TeV and to four different perturbative QCD calculations. Its rapidity dependence is also tested combining the ALICE and LHCb measurements in pp collisions at $\sqrt{s}=5.02$ TeV. This measurement will allow for a more accurate determination of the nuclear modification factor in p-Pb and Pb-Pb collisions performed at the same nucleon-nucleon centre-of-mass energy.

The ALICE collaboration at the CERN LHC reports novel measurements of jet substructure in pp collisions at $\sqrt{s}$= 7 TeV and central Pb-Pb collisions at $\sqrt{s_{\rm{NN}}}$ = 2.76 TeV. Jet substructure of track-based jets is explored via iterative declustering and grooming techniques. We present the measurement of the momentum sharing of two-prong substructure exposed via grooming, the $z_{\rm{g}}$, and its dependence on the opening angle, in both pp and Pb-Pb collisions. We also present the first measurement of the distribution of the number of branches obtained in the iterative declustering of the jet, which is interpreted as the number of its hard splittings. In Pb-Pb collisions, we observe a suppression of symmetric splittings at large opening angles and an enhancement of splittings at small opening angles relative to pp collisions, with no significant modification of the number of splittings. The results are compared to predictions from various Monte Carlo event generators to test the role of important concepts in the evolution of the jet in the medium such as color coherence.

We present measurements of Underlying Event observables in pp collisions at $\sqrt{s}$ = 0.9 and 7 TeV. The analysis is performed as a function of the highest charged-particle transverse momentum $p_{\rm T, LT}$ in the event. Different regions are defined with respect to the azimuthal direction of the leading (highest transverse momentum) track: Toward, Transverse and Away. The Toward and Away regions collect the fragmentation products of the hardest partonic interaction. The Transverse region is expected to be most sensitive to the Underlying Event activity. The study is performed with charged particles above three different $p_{\rm T}$ thresholds: 0.15, 0.5 and 1.0 GeV/$c$. In the Transverse region we observe an increase in the multiplicity of a factor 2-3 between the lower and higher collision energies, depending on the track $p){\rm T}$ threshold considered. Data are compared to Pythia 6.4, Pythia 8.1 and Phojet. On average, all models considered underestimate the multiplicity and summed $p_{\rm T}$ in the Transverse region by about 10-30%.

A detailed study of pseudorapidity densities and multiplicity distributions of primary charged particles produced in proton-proton collisions, at $\sqrt{s} =$ 0.9, 2.36, 2.76, 7 and 8 TeV, in the pseudorapidity range $|\eta|<2$, was carried out using the ALICE detector. Measurements were obtained for three event classes: inelastic, non-single diffractive and events with at least one charged particle in the pseudorapidity interval $|\eta|<1$. The use of an improved track-counting algorithm combined with ALICE's measurements of diffractive processes allows a higher precision compared to our previous publications. A KNO scaling study was performed in the pseudorapidity intervals $|\eta|<$ 0.5, 1.0 and 1.5. The data are compared to other experimental results and to models as implemented in Monte Carlo event generators PHOJET and recent tunes of PYTHIA6, PYTHIA8 and EPOS.

We present the measurement of a new set of jet shape observables for track-based jets in central Pb-Pb collisions at $\sqrt{s_{\mathrm{NN}}} = 2.76$ TeV. The set of jet shapes includes the first radial moment or angularity, $g$; the momentum dispersion, $p_{\rm T}D$; and the difference between the leading and sub-leading constituent track transverse momentum, $LeSub$. These observables provide complementary information on the jet fragmentation and can constrain different aspects of the theoretical description of jet-medium interactions. The jet shapes were measured for a small resolution parameter $R = 0.2$ and were fully corrected to particle level. The observed jet shape modifications indicate that in-medium fragmentation is harder and more collimated than vacuum fragmentation as obtained by PYTHIA calculations, which were validated with the measurements of the jet shapes in proton-proton collisions at $\sqrt{s} = 7$ TeV. The comparison of the measured distributions to templates for quark and gluon-initiated jets indicates that in-medium fragmentation resembles that of quark jets in vacuum. We further argue that the observed modifications are not consistent with a totally coherent energy loss picture where the jet loses energy as a single colour charge, suggesting that the medium resolves the jet structure at the angular scales probed by our measurements ($R=0.2$). Furthermore, we observe that small-$R$ jets can help to isolate purely energy loss effects from other effects that contribute to the modifications of the jet shower in medium such as the correlated background or medium response.