The distributions of quarks in the pion and nucleon are extracted from measurements of the reaction π−N→μ+μ−X at 253 GeV/c in a naive Drell-Yan analysis, as well as QCD-corrected analyses at leading-log and next-to-leading-log order. As xπ→1 the pion structure function shows a term that varies as 1mμμ4, which we interpret as a higher-twist effect. Additionally, the angular distribution of the μ+ in the muon-pair rest frame tends towards sin2θ as xπ→1 and as mμμ→0 in a manner consistent with higher-twist effects. When the strongly mass-dependent higher-twist effects are included as part of the pion structure function, the nucleon structure function agrees well with leading-twist results from deeply inelastic lepton-hadron scattering. A significant advance of the present work is the extension of the analysis to low masses by the subtraction of the Jψ and ψ′ resonances from the continuum. Our analysis covers the kinematic range 0.4
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