The inclusive production rates and differential cross-sections of photons and mesons with a final state containing photons have been measured with the OPAL detector at LEP. The light mesons covered by the measurements are the \pi^0, \eta, \rho(770)+-, \omega(782), \eta'(958) and a_0(980)+-. The particle multiplicities per hadronic Z^0 decay, extrapolated to the full energy range, are: <n_\gamma> = 20.97 +/- 0.02 +/- 1.15, <n_\pi^0> = 9.55 +/- 0.06 +/- 0.75, <n_\eta> = 0.97 +/- 0.03 +/- 0.11, <n_\rho^+-> = 2.40 +/- 0.06 +/- 0.43, <n_\omega> = 1.04 +/- 0.04 +/- 0.14, <n_\eta> = 0.14 +/- 0.01 +/- 0.02, <n_a_0+-> = 0.27 +/- 0.04 +/- 0.10. where the first errors are statistical and the second systematic. In general, the results are in agreement with the predictions of the JETSET and HERWIG Monte Carlo models.
The helicity density matrix elements rho[00] of rho(770)+- and omega(782) mesons produced in Z decays have been measured using the OPAL detector at LEP. Over the measured meson energy range, the values are compatible with 1/3, corresponding to a statistical mix of helicity -1, 0 and +1 states. For the highest accessible scaled energy range 0.3 < x_E < 0.6, the measured rho[00] values of the rho(770)+- and the omega are 0.373 +- 0.052 and 0.142 +- 0.114, respectively. These results are compared to measurements of other vector mesons.