This paper presents the measurements of $\pi^{\pm}$, $\rm{K}^{\pm}$, $\rm{p}$ and $\bar{\rm{p}}$ transverse momentum ($p_{\rm{T}}$) spectra as a function of charged-particle multiplicity density in proton-proton (pp) collisions at $\sqrt{s}$ = 13 TeV with the ALICE detector at the LHC. Such study allows us to isolate the center-of-mass energy dependence of light-flavour particle production. The measurements reported here cover a $p_{\rm{T}}$ range from 0.1 GeV/$c$ to 20 GeV/$c$ and are done in the rapidity interval $|y|<0.5$. The $p_{\rm{T}}$-differential particle ratios exhibit an evolution with multiplicity, similar to that observed in pp collisions at $\sqrt{s}$ = 7 TeV, which is qualitatively described by some of the hydrodynamical and pQCD-inspired models discussed in this paper. Furthermore, the $p_{\rm{T}}$-integrated hadron-to-pion yield ratios measured in pp collisions at two different center-of-mass energies are consistent when compared at similar multiplicities. This also extends to strange and multistrange hadrons, suggesting that, at LHC energies, particle hadrochemistry scales with particle multiplicity the same way under different collision energies and colliding systems.

The production of $\phi$ mesons has been studied in pp collisions at LHC energies with the ALICE detector via the dimuon decay channel in the rapidity region $2.5 < y < 4$. Measurements of the differential cross section ${\rm d}^2\sigma/{\rm d}y {\rm d}p_{\rm T}$ are presented as a function of the transverse momentum ($p_{\rm T}$) at the center-of-mass energies $\sqrt{s}=5.02$, 8 and 13 TeV and compared with the ALICE results at midrapidity. The differential cross sections at $\sqrt{s}=5.02$ and 13 TeV are also studied in several rapidity intervals as a function of $p_{\rm T}$, and as a function of rapidity in three $p_{\rm T}$ intervals. A hardening of the $p_{\rm T}$-differential cross section with the collision energy is observed, while, for a given energy, $p_{\rm T}$ spectra soften with increasing rapidity and, conversely, rapidity distributions get slightly narrower at increasing $p_{\rm T}$. The new results, complementing the published measurements at $\sqrt{s}=2.76$ and 7 TeV, allow one to establish the energy dependence of $\phi$ meson production and to compare the measured cross sections with phenomenological models. None of the considered models manages to describe the evolution of the cross section with $p_{\rm T}$ and rapidity at all the energies.

The production rates and the transverse momentum distribution of strange hadrons at mid-rapidity ($\ |y\ | < 0.5$) are measured in proton-proton collisions at $\sqrt{s}$ = 13 TeV as a function of the charged particle multiplicity, using the ALICE detector at the LHC. The production rates of $\rm{K}^{0}_{S}$, $\Lambda$, $\Xi$, and $\Omega$ increase with the multiplicity faster than what is reported for inclusive charged particles. The increase is found to be more pronounced for hadrons with a larger strangeness content. Possible auto-correlations between the charged particles and the strange hadrons are evaluated by measuring the event-activity with charged particle multiplicity estimators covering different pseudorapidity regions. When comparing to lower energy results, the yields of strange hadrons are found to depend only on the mid-rapidity charged particle multiplicity. Several features of the data are reproduced qualitatively by general purpose QCD Monte Carlo models that take into account the effect of densely-packed QCD strings in high multiplicity collisions. However, none of the tested models reproduce the data quantitatively. This work corroborates and extends the ALICE findings on strangeness production in proton-proton collisions at 7 TeV.

The production of $\pi^{\pm}$, $\rm{K}^{\pm}$, $\rm{K}^{0}_{S}$, $\rm{K}^{*}(892)^{0}$, $\rm{p}$, $\phi(1020)$, $\Lambda$, $\Xi^{-}$, $\Omega^{-}$, and their antiparticles was measured in inelastic proton-proton (pp) collisions at a center-of-mass energy of $\sqrt{s}$ = 13 TeV at midrapidity ($|y|<0.5$) as a function of transverse momentum ($p_{\rm{T}}$) using the ALICE detector at the CERN LHC. Furthermore, the single-particle $p_{\rm{T}}$ distributions of $\rm{K}^{0}_{S}$, $\Lambda$, and $\overline{\Lambda}$ in inelastic pp collisions at $\sqrt{s}$ = 7 TeV are reported here for the first time. The $p_{\rm{T}}$ distributions are studied at midrapidity within the transverse momentum range $0\leq p_{\rm{T}}\leq20$ GeV/$c$, depending on the particle species. The $p_{\rm{T}}$ spectra, integrated yields, and particle yield ratios are discussed as a function of collision energy and compared with measurements at lower $\sqrt{s}$ and with results from various general-purpose QCD-inspired Monte Carlo models. A hardening of the spectra at high $p_{\rm{T}}$ with increasing collision energy is observed, which is similar for all particle species under study. The transverse mass and $x_{\rm{T}}\equiv2p_{\rm{T}}/\sqrt{s}$ scaling properties of hadron production are also studied. As the collision energy increases from $\sqrt{s}$ = 7 to 13 TeV, the yields of non- and single-strange hadrons normalized to the pion yields remain approximately constant as a function of $\sqrt{s}$, while ratios for multi-strange hadrons indicate enhancements. The $p_{\rm{T}}$-differential cross sections of $\pi^{\pm}$, $\rm{K}^{\pm}$ and $\rm{p}$ ($\overline{\rm{p}}$) are compared with next-to-leading order perturbative QCD calculations, which are found to overestimate the cross sections for $\pi^{\pm}$ and $\rm{p}$ ($\overline{\rm{p}}$) at high $p_{\rm{T}}$.

Measurements of identified hadrons as a function of the charged-particle multiplicity in pp collisions enable a search for the onset of collective effects in small collision systems. With such measurements, it is possible to study the mechanisms that determine the shapes of hadron transverse momentum ($p_{\rm{T}}$) spectra, to search for possible modifications of the yields of short-lived hadronic resonances due to scattering effects in the hadron-gas phase, and to investigate different explanations for the multiplicity evolution of strangeness production provided by phenomenological models. In this paper, these topics are addressed through measurements of the $\rm{K}^{*}(892)^{0}$ and $\phi(1020)$ mesons at midrapidity in pp collisions at $\sqrt{s}$ = 13 TeV as a function of the charged-particle multiplicity. The results include the $p_{\rm{T}}$ spectra, $p_{\rm{T}}$-integrated yields, mean transverse momenta, and the ratios of the yields of these resonances to those of longer-lived hadrons. Comparisons with results from other collision systems and energies, as well as predictions from phenomenological models, are also discussed.

Angular correlations of heavy-flavour and charged particles in high-energy proton-proton collisions are sensitive to the production mechanisms of heavy quarks and to their fragmentation as well as hadronisation processes. The measurement of the azimuthal-correlation function of prompt D mesons with charged particles in proton-proton collisions at a centre-of-mass energy of $\sqrt{s} = 13$ TeV with the ALICE detector is reported, considering D$^{0}$, D$^{+}$, and D$^{*+}$ mesons in the transverse-momentum interval $3 < p_{\rm T} < 36$ GeV/$c$ at midrapidity ($|y| < 0.5$), and charged particles with $p_{\rm T} > 0.3$ GeV/$c$ and pseudorapidity $|\eta| < 0.8$. This measurement has an improved precision and provides an extended transverse-momentum coverage compared to previous ALICE measurements at lower energies. The study is also performed as a function of the charged-particle multiplicity, showing no modifications of the correlation function with multiplicity within uncertainties. The properties and the transverse-momentum evolution of the near- and away-side correlation peaks are studied and compared with predictions from various Monte Carlo event generators. Among those considered, PYTHIA8 and POWHEG+PYTHIA8 provide the best description of the measured observables. The obtained results can provide guidance on tuning the generators.

The study of (anti-)deuteron production in pp collisions has proven to be a powerful tool to investigate the formation mechanism of loosely bound states in high energy hadronic collisions. In this paper the production of (anti-)deuterons is studied as a function of the charged particle multiplicity in inelastic pp collisions at $\sqrt{s}=13$ TeV using the ALICE experiment. Thanks to the large number of accumulated minimum bias events, it has been possible to measure (anti-)deuteron production in pp collisions up to the same charged particle multiplicity ($\rm{d} N_{ch}/\rm{d}\eta\sim26$) as measured in p-Pb collisions at similar centre-of-mass energies. Within the uncertainties, the deuteron yield in pp collisions resembles the one in p-Pb interactions, suggesting a common formation mechanism behind the production of light nuclei in hadronic interactions. In this context the measurements are compared with the expectations of coalescence and Statistical Hadronisation Models (SHM).

The $p_{\rm T}$-differential cross sections of prompt charm-strange baryons $\Xi^0_{\rm c}$ and $\Xi^+_{\rm c}$ were measured at midrapidity ($|y| < 0.5$) in proton$-$proton (pp) collisions at a centre-of-mass energy $\sqrt{s}=13$ TeV with the ALICE detector at the LHC. The $\Xi^0_{\rm c}$ baryon was reconstructed via both the semileptonic decay ($\Xi^{-}{\rm e^{+}}\nu_{\rm e}$) and the hadronic decay ($\Xi^{-}{\rm \pi^{+}}$) channels. The $\Xi^+_{\rm c}$ baryon was reconstructed via the hadronic decay ($\Xi^{-}\pi^{+}\pi^{+}$) channel. The branching-fraction ratio $\rm {\rm BR}(\Xi_c^0\rightarrow \Xi^-e^+\nu_e)/\rm {\rm BR}(\Xi_c^0\rightarrow \Xi^{-}\pi^+)=$ 1.38 $\pm$ 0.14 (stat) $\pm$ 0.22 (syst) was measured with a total uncertainty reduced by a factor of about 3 with respect to the current world average reported by the Particle Data Group. The transverse momentum ($p_{\rm T}$) dependence of the $\Xi^0_{\rm c}$- and $\Xi^+_{\rm c}$-baryon production relative to the ${\rm D^0}$-meson and to the $\Sigma^{0,+,++}_{\rm c}$- and $\Lambda^+_{\rm c}$-baryon production are reported. The baryon-to-meson ratio increases towards low $p_{\rm T}$ up to a value of approximately 0.3. The measurements are compared with various models that take different hadronisation mechanisms into consideration. The results provide stringent constraints to these theoretical calculations and additional evidence that different processes are involved in charm hadronisation in electron$-$positron ($\rm e^+e^-$) and hadronic collisions.

Deuteron production in high-energy collisions is sensitive to the space-time evolution of the collision system, and is typically described by a coalescence mechanism. For the first time, we present results on jet-associated deuteron production in \pp collisions at $\sqrt{s}=13$ TeV, providing an opportunity to test the established picture for deuteron production in events with a hard scattering. Using a trigger particle with high transverse-momentum ($p_{\rm T}>5$ GeV/$c$) as a proxy for the presence of a jet at midrapidity, we observe a measurable population of deuterons being produced around the jet proxy. The associated deuteron yield measured in a narrow angular range around the trigger particle differs by 2.4-4.8 standard deviations from the uncorrelated background. The data are described by PYTHIA model calculations featuring baryon coalescence.

Understanding the production mechanism of light (anti)nuclei is one of the key challenges of nuclear physics and has important consequences for astrophysics, since it provides an input for indirect dark-matter searches in space. In this paper, the latest results about the production of light (anti)nuclei in pp collisions at $\sqrt{s} = 13$ TeV are presented, focusing on the comparison with the predictions of coalescence and thermal models. For the first time, the coalescence parameters $B_2$ for deuterons and $B_3$ for helions are compared with parameter-free theoretical predictions that are directly constrained by the femtoscopic measurement of the source radius in the same event class. A fair description of the data with a Gaussian wave function is observed for both deuteron and helion, supporting the coalescence mechanism for the production of light (anti)nuclei in pp collisions. This method paves the way for future investigations of the internal structure of more complex nuclear clusters, including the hypertriton.