The study of (anti-)deuteron production in pp collisions has proven to be a powerful tool to investigate the formation mechanism of loosely bound states in high energy hadronic collisions. In this paper the production of (anti-)deuterons is studied as a function of the charged particle multiplicity in inelastic pp collisions at $\sqrt{s}=13$ TeV using the ALICE experiment. Thanks to the large number of accumulated minimum bias events, it has been possible to measure (anti-)deuteron production in pp collisions up to the same charged particle multiplicity ($\rm{d} N_{ch}/\rm{d}\eta\sim26$) as measured in p-Pb collisions at similar centre-of-mass energies. Within the uncertainties, the deuteron yield in pp collisions resembles the one in p-Pb interactions, suggesting a common formation mechanism behind the production of light nuclei in hadronic interactions. In this context the measurements are compared with the expectations of coalescence and Statistical Hadronisation Models (SHM).

The cross section of jets reconstructed from charged particles is measured in the transverse momentum range of $5<p_\mathrm{T}<100\ \mathrm{GeV}/c$ in pp collisions at the center-of-mass energy of $\sqrt{s} = 5.02\ \mathrm{TeV}$ with the ALICE detector. The jets are reconstructed using the anti-$k_\mathrm{T}$ algorithm with resolution parameters $R=0.2$, $0.3$, $0.4$, and $0.6$ in the pseudorapidity range $|\eta|< 0.9-R$. The charged jet cross sections are compared with the leading order (LO) and to next-to-leading order (NLO) perturbative Quantum ChromoDynamics (pQCD) calculations. It was found that the NLO calculations agree better with the measurements. The cross section ratios for different resolution parameters were also measured. These ratios increase from low $p_\mathrm{T}$ to high $p_\mathrm{T}$ and saturate at high $p_\mathrm{T}$, indicating that jet collimation is larger at high $p_\mathrm{T}$ than at low $p_\mathrm{T}$. These results provide a precision test of pQCD predictions and serve as a baseline for the measurement in Pb$-$Pb collisions at the same energy to quantify the effects of the hot and dense medium created in heavy-ion collisions at the LHC.

The study of the strength and behaviour of the antikaon-nucleon ($\mathrm{\overline{K}N}$) interaction constitutes one of the key focuses of the strangeness sector in low-energy Quantum Chromodynamics (QCD). In this letter a unique high-precision measurement of the strong interaction between kaons and protons, close and above the kinematic threshold, is presented. The femtoscopic measurements of the correlation function at low pair-frame relative momentum of (K$^+$ p $\oplus$ K$^-$ $\overline{\mathrm{p}}$) and (K$^-$ p $\oplus$ K$^+$ $\overline{\mathrm{p}}$) pairs measured in pp collisions at $\sqrt{s}$ = 5, 7 and 13 TeV are reported. A structure observed around a relative momentum of 58 MeV/$c$ in the measured correlation function of (K$^-$ p $\oplus$ K$^+$ $\overline{\mathrm{p}}$) with a significance of 4.4. $\sigma$ constitutes the first experimental evidence for the opening of the $(\mathrm{\overline{K}^0 n} \oplus \mathrm{K^0 \overline{n}})$ isospin breaking channel due to the mass difference between charged and neutral kaons. The measured correlation functions have been compared to J\"{u}lich and Kyoto models in addition to the Coulomb potential. The high-precision data at low relative momenta presented in this work prove femtoscopy to be a powerful complementary tool to scattering experiments and provide new constraints above the $\mathrm{\overline{K}N}$ threshold for low-energy QCD chiral models.

We present results on transverse momentum ($p_{\rm T}$) and rapidity ($y$) differential production cross sections, mean transverse momentum and mean transverse momentum square of inclusive J/$\psi$ and $\psi(2S)$ at forward rapidity ($2.5<y<4$) as well as $\psi(2S)$-to-J/$\psi$ cross section ratios. These quantities are measured in pp collisions at center of mass energies $\sqrt{s}=5.02$ and 13 TeV with the ALICE detector. Both charmonium states are reconstructed in the dimuon decay channel, using the muon spectrometer. A comprehensive comparison to inclusive charmonium cross sections measured at $\sqrt{s}=2.76$, 7 and 8 TeV is performed. A comparison to non-relativistic quantum chromodynamics and fixed-order next-to-leading logarithm calculations, which describe prompt and non-prompt charmonium production respectively, is also presented. A good description of the data is obtained over the full $p_{\rm T}$ range, provided that both contributions are summed. In particular, it is found that for $p_{\rm T}>15$ GeV/$c$ the non-prompt contribution reaches up to 50% of the total charmonium yield.

The pseudorapidity ($\eta$) and transverse-momentum ($p_{\rm T}$) distributions of charged particles produced in proton-proton collisions are measured at the centre-of-mass energy $\sqrt{s}$ = 13 TeV. The pseudorapidity distribution in $|\eta|<$ 1.8 is reported for inelastic events and for events with at least one charged particle in $|\eta|<$ 1. The pseudorapidity density of charged particles produced in the pseudorapidity region $|\eta|<$ 0.5 is 5.31 $\pm$ 0.18 and 6.46 $\pm$ 0.19 for the two event classes, respectively. The transverse-momentum distribution of charged particles is measured in the range 0.15 $<$ $p_{\rm T}$ $<$ 20 GeV/c and $|\eta|<$ 0.8 for events with at least one charged particle in $|\eta|<$ 1. The correlation between transverse momentum and particle multiplicity is also investigated by studying the evolution of the spectra with event multiplicity. The results are compared with calculations from PYTHIA and EPOS Monte Carlo generators.

The measurement of dielectron production is presented as a function of invariant mass and transverse momentum ($p_{\rm T}$) at midrapidity ($|y_{\rm e}|<0.8$) in proton-proton (pp) collisions at a centre-of-mass energy of $\sqrt{s}=13$ TeV. The contributions from light-hadron decays are calculated from their measured cross sections in pp collisions at $\sqrt{s}=7$ TeV or 13 TeV. The remaining continuum stems from correlated semileptonic decays of heavy-flavour hadrons. Fitting the data with templates from two different MC event generators, PYTHIA and POWHEG, the charm and beauty cross sections at midrapidity are extracted for the first time at this collision energy: ${\rm d}\sigma_{\rm c\bar{c}}/{\rm d}y|_{y=0}=974\pm138(\rm{stat.})\pm140(\rm{syst.})~\mu{\rm b}$ and ${\rm d}\sigma_{\rm b\bar{b}}/{\rm d}y|_{y=0}=79\pm14(\rm{stat.})\pm11(\rm{syst.})~\mu{\rm b}$ using PYTHIA simulations and ${\rm d}\sigma_{\rm c\bar{c}}/{\rm d}y|_{y=0}=1417\pm184(\rm{stat.})\pm204(\rm{syst.})~\mu{\rm b}$ and ${\rm d}\sigma_{\rm b\bar{b}}/{\rm d}y|_{y=0}=48\pm14(\rm{stat.})\pm7(\rm{syst.})~\mu{\rm b}$ for POWHEG. These values, whose uncertainties are fully correlated between the two generators, are consistent with extrapolations from lower energies. The different results obtained with POWHEG and PYTHIA imply different kinematic correlations of the heavy-quark pairs in these two generators. Furthermore, comparisons of dielectron spectra in inelastic events and in events collected with a trigger on high charged-particle multiplicities are presented in various $p_{\rm T}$ intervals. The differences are consistent with the already measured scaling of light-hadron and open-charm production at high charged-particle multiplicity as a function of $p_{\rm T}$. Upper limits for the contribution of virtual direct photons are extracted at 90% confidence level and found to be in agreement with pQCD calculations.

Measurements of anisotropic flow coefficients ($v_n$) and their cross-correlations using two- and multi-particle cumulant methods are reported in collisions of pp at $\sqrt{s} = 13$ TeV, p-Pb at $\sqrt{s_{_{\rm NN}}} = 5.02$ TeV, Xe-Xe at $\sqrt{s_{_{\rm NN}}} = 5.44$ TeV, and Pb-Pb at $\sqrt{s_{_{\rm NN}}} = 5.02$ TeV recorded with the ALICE detector. The multiplicity dependence of $v_n$ is studied in a very wide range from 20 to 3000 particles produced in the mid-rapidity region $|\eta|<0.8$ for the transverse momentum range $0.2 < p_{\rm T} < 3.0$ GeV/$c$. An ordering of the coefficients $v_2 > v_3 > v_4$ is found in pp and p-Pb collisions, similar to that seen in large collision systems, while a weak $v_2$ multiplicity dependence is observed relative to nucleus-nucleus collisions in the same multiplicity range. Using a novel subevent method, $v_{2}$ measured with four-particle cumulants is found to be compatible with that from six-particle cumulants in pp and p-Pb collisions. The magnitude of the correlation between $v_n^2$ and $v_m^2$, evaluated with the symmetric cumulants SC$(m,n)$ is observed to be positive at all multiplicities for $v_2$ and $v_4$, while for $v_2$ and $v_3$ it is negative and changes sign for multiplicities below 100, which may indicate a different $v_n$ fluctuation pattern in this multiplicity range. The observed long-range multi-particle azimuthal correlations in high multiplicity pp and p-Pb collisions can neither be described by PYTHIA 8 nor by IP-Glasma+MUSIC+UrQMD model calculations, and hence provide new insights into the understanding of collective effects in small collision systems.

This article reports measurements characterizing the Underlying Event (UE) associated with hard scatterings at midrapidity in pp collisions at $\sqrt{s}=13$ TeV. The hard scatterings are identified by the leading particle, the charged particle with the highest transverse momentum ($p_{\rm T}^{\rm leading}$) in the event. Charged-particle number and summed transverse-momentum densities are measured in different azimuthal regions defined with respect to the leading particle direction: Toward, Transverse, and Away. The Toward and Away regions contain the fragmentation products of the hard scatterings in addition to the UE contribution, whereas particles in the Transverse region are expected to originate predominantly from the UE. The study is performed as a function of $p_{\rm T}^{\rm leading}$ with three different $p_{\rm T}$ thresholds for the associated particles, $p_{\rm T}^{\rm min} >$ 0.15, 0.5, and 1.0 GeV/$c$. The charged-particle density in the Transverse region rises steeply for low values of $p_{\rm T}^{\rm leading}$ and reaches a plateau. The results confirm the trend that the charged-particle density in the Transverse region shows a stronger increase with $\sqrt{s}$ than the inclusive charged-particle density at midrapidity. The UE activity is increased by approximately 20% when going from 7 to 13 TeV. The plateau in the Transverse region ($5 < p_{\rm T}^{\rm leading} < ~ 40$ GeV/$c$ ) is further characterized by the probability distribution of its charged-particle multiplicity normalized to its average value (relative transverse activity, $R_{T}$) and the mean transverse momentum as a function of $R_{T}$. Experimental results are compared to model calculations using PYTHIA 8 and EPOS LHC. The overall agreement between models and data is within 30%. These measurements provide new insights on the interplay between hard scatterings and the associated UE in pp collisions.

This Letter presents the first direct investigation of the p-$\Sigma^{0}$ interaction, using the femtoscopy technique in high-multiplicity pp collisions at $\sqrt{s}$ = 13 TeV measured by the ALICE detector. The $\Sigma^{0}$ is reconstructed via the decay channel to $\Lambda \gamma$, and the subsequent decay of $\Lambda$ to p$\pi^-$. The photon is detected via the conversion in material to e$^{+}$e$^{-}$ pairs exploiting the unique capability of the ALICE detector to measure electrons at low transverse momenta. The measured p-$\Sigma^{0}$ correlation indicates a shallow strong interaction. The comparison of the data to several theoretical predictions obtained employing the $Correlation~Analysis~Tool~using~the~Schr\"odinger~Equation$ (CATS) and the Lednick\'y-Lyuboshits approach shows that the current experimental precision does not yet allow to discriminate between different models, as it is the case for the available scattering and hypernuclei data. Nevertheless, the p-$\Sigma^{0}$ correlation function is found to be sensitive to the strong interaction, and driven by the interplay of the different spin and isospin channels. This pioneering study demonstrates the feasibility of a femtoscopic measurement in the p-$\Sigma^{0}$ channel and with the expected larger data samples in LHC Run 3 and Run 4, the p-$\Sigma^{0}$ interaction will be constrained with high precision.

Deuteron production in high-energy collisions is sensitive to the space-time evolution of the collision system, and is typically described by a coalescence mechanism. For the first time, we present results on jet-associated deuteron production in \pp collisions at $\sqrt{s}=13$ TeV, providing an opportunity to test the established picture for deuteron production in events with a hard scattering. Using a trigger particle with high transverse-momentum ($p_{\rm T}>5$ GeV/$c$) as a proxy for the presence of a jet at midrapidity, we observe a measurable population of deuterons being produced around the jet proxy. The associated deuteron yield measured in a narrow angular range around the trigger particle differs by 2.4-4.8 standard deviations from the uncorrelated background. The data are described by PYTHIA model calculations featuring baryon coalescence.