Correlations between mean transverse momentum $[p_{\rm T}]$ and anisotropic flow coefficients $v_{\rm 2}$ or $v_{\rm 3}$ are measured as a function of centrality in Pb$-$Pb and Xe$-$Xe collisions at $\sqrt{s_{\rm NN}} = 5.02$ TeV and 5.44 TeV, respectively, with ALICE. In addition, the recently proposed higher-order correlation between $[p_{\rm T}]$, $v_{\rm 2}$, and $v_{\rm 3}$ is measured for the first time, which shows an anticorrelation for the presented centrality ranges. These measurements are compared with hydrodynamic calculations using IP-Glasma and $\rm T_{R}ENTo$ initial-state shapes, the former based on the Color Glass Condensate effective theory with gluon saturation, and the latter a parameterized model with nucleons as the relevant degrees of freedom. The data are better described by the IP-Glasma rather than the $\rm T_{R}ENTo$ based calculations. In particular, Trajectum and JETSCAPE predictions, both based on the $\rm T_{R}ENTo$ initial state model but with different parameter settings, fail to describe the measurements. As the correlations between $[p_{\rm T}]$ and $v_{\rm n}$ are mainly driven by the correlations of the size and the shape of the system in the initial state, these new studies pave a novel way to characterize the initial state and help pin down the uncertainty of the extracted properties of the quark$-$gluon plasma recreated in relativistic heavy-ion collisions.

Measurements of the elliptic flow coefficient relative to the collision plane defined by the spectator neutrons $v_2${$\Psi_{\rm SP}$} in collisions of Pb ions at center-of-mass energy per nucleon-nucleon pair $\sqrt{s_{\rm NN}}$=2.76 TeV and Xe ions at $\sqrt{s_{\rm NN}}$=5.44 TeV are reported. The results are presented for charged particles produced at midrapidity as a function of centrality and transverse momentum. The ratio between $v_2${$\Psi_{\rm SP}$} and the elliptic flow coefficient relative to the participant plane $v_2$4, estimated using four-particle correlations, deviates by up to 20% from unity depending on centrality. This observation differs strongly from the magnitude of the corresponding eccentricity ratios predicted by the TRENTo and the elliptic power models of initial state fluctuations that are tuned to describe the participant plane anisotropies. The differences can be interpreted as a decorrelation of the neutron spectator plane and the reaction plane because of fragmentation of the remnants from the colliding nuclei, which points to an incompleteness of current models of initial state fluctuations. A significant transverse momentum dependence of the ratio $v_2${$\Psi_{\rm SP}$}/$v_2${4} is observed in all but the most central collisions, which may help to understand whether momentum anisotropies at low and intermediate transverse momentum have a common origin in initial state fluctuations. The ratios of $v_2${$\Psi_{\rm SP}$} and $v_2${4} to the corresponding initial state eccentricities for Xe-Xe and Pb-Pb collisions at similar initial entropy density show a difference of $(7.0 \pm 0.9)$% with an additional variation of +1.8% when including RHIC data in the TRENTo parameter extraction. These observations provide new experimental constraints for viscous effects in the hydrodynamic modeling of the expanding quark-gluon plasma.

Multiplicity ($N_{\rm ch}$) distributions and transverse momentum ($p_{\rm T}$) spectra of inclusive primary charged particles in the kinematic range of $|\eta| < 0.8$ and 0.15 GeV/$c$$< p_{T} <$ 10 GeV/$c$ are reported for pp, p-Pb, Xe-Xe and Pb-Pb collisions at centre-of-mass energies per nucleon pair ranging from $\sqrt{s_{\rm NN}} = 2.76$ TeV up to $13$ TeV. A sequential two-dimensional unfolding procedure is used to extract the correlation between the transverse momentum of primary charged particles and the charged-particle multiplicity of the corresponding collision. This correlation sharply characterises important features of the final state of a collision and, therefore, can be used as a stringent test of theoretical models. The multiplicity distributions as well as the mean and standard deviation derived from the $p_{\rm T}$ spectra are compared to state-of-the-art model predictions. Providing these fundamental observables of bulk particle production consistently across a wide range of collision energies and system sizes can serve as an important input for tuning Monte Carlo event generators.

The pseudorapidity dependence of elliptic ($v_2$), triangular ($v_3$), and quadrangular ($v_4$) flow coefficients of charged particles measured in Pb-Pb collisions at a centre-of-mass energy per nucleon pair of $\sqrt{s_{\rm NN}}=5.02$ TeV and in Xe-Xe collisions at $\sqrt{s_{\rm NN}}=5.44$ TeV with ALICE at the LHC are presented. The measurements are performed in the pseudorapidity range $-3.5 < \eta < 5$ for various centrality intervals using two- and multi-particle cumulants with the subevent method. The flow probability density function (p.d.f.) is studied with the ratio of flow coefficient $v_2$ calculated with four- and two-particle cumulant, and suggests that the variance of flow p.d.f. is independent of pseudorapidity. The decorrelation of the flow vector in the longitudinal direction is probed using two-particle correlations. The results measured with respect to different reference regions in pseudorapidity exhibit differences, argued to be a result of saturating decorrelation effect above a certain pseudorapidity separation, in contrast to previous publications which assign this observation to non-flow effects. The results are compared to $3+1$ dimensional hydrodynamic and the AMPT transport model calculations. Neither of the models is able to simultaneously describe the pseudorapidity dependence of measurements of anisotropic flow and its fluctuations. The results presented in this work highlight shortcomings in our current understanding of initial conditions and subsequent system expansion in the longitudinal direction. Therefore, they provide input for its improvement.

The production of J/$\psi$ is measured as a function of charged-particle multiplicity at forward rapidity in proton$-$proton (pp) collisions at center-of-mass energies $\sqrt{s} =$ 5.02 and 13 TeV. The J/$\psi$ mesons are reconstructed via their decay into dimuons in the rapidity interval (2.5 $< y <$ 4.0), whereas the charged-particle multiplicity density (${\rm d}N_{\rm{ch}}/{\rm d}\eta$) is measured at midrapidity $(|\eta| < 1)$. The production rate as a function of multiplicity is reported as the ratio of the yield in a given multiplicity interval to the multiplicity-integrated one. This observable shows a linear increase with charged-particle multiplicity normalized to the corresponding average value for inelastic events (${{\rm d}N_{\rm ch}/{\rm d}\eta}/{\langle {\rm d}N_{\rm ch}/{\rm d}\eta \rangle}$), at both the colliding energies. Measurements are compared with available ALICE results at midrapidity and theoretical model calculations. First measurement of the mean transverse momentum ($\langle p_{\mathrm{T}}\rangle$) of J/$\psi$ in pp collisions exhibits an increasing trend as a function of ${{\rm d}N_{\rm ch}/{\rm d}\eta}/{\langle {\rm d}N_{\rm ch}/{\rm d}\eta \rangle}$ showing a saturation towards high charged-particle multiplicities.

Measurements of elliptic ($v_2$) and triangular ($v_3$) flow coefficients of $\pi^{\pm}$, K$^{\pm}$, p+$\rm \overline{p}$, K$^0_{\rm S}$, and $\Lambda + \overline{\Lambda}$ obtained with the scalar product method in Xe-Xe collisions at $\sqrt{s_{\rm NN}}$ = 5.44 TeV are presented. The results are obtained in the rapidity range $\left | y \right |<0.5$ and reported as a function of transverse momentum, $p_{\rm T}$, for several collision centrality classes. The flow coefficients exhibit a particle mass dependence for $p_{\rm T}<3$ GeV/$c$, while a grouping according to particle type (i.e., meson and baryon) is found at intermediate transverse momenta (3< $p_{\rm T}$ <8 GeV/$c$). The magnitude of the baryon $v_{2}$ is larger than that of mesons up to $p_{\rm T}$ = 6 GeV/$c$. The centrality dependence of the shape evolution of the $p_{\rm T}$-differential $v_2$ is studied for the various hadron species. The $v_2$ coefficients of $\pi^{\pm}$, K$^{\pm}$, and p+$\rm \overline{p}$ are reproduced by MUSIC hydrodynamic calculations coupled to a hadronic cascade model (UrQMD) for $p_{\rm T} <1$ GeV/$c$. A comparison with $v_{\rm n}$ measurements in the corresponding centrality intervals in Pb-Pb collisions at $\sqrt{s_{\rm NN}}$ = 5.02 TeV yields an enhanced $v_2$ in central collisions and diminished value in semicentral collisions.

A detailed study of pseudorapidity densities and multiplicity distributions of primary charged particles produced in proton-proton collisions, at $\sqrt{s} =$ 0.9, 2.36, 2.76, 7 and 8 TeV, in the pseudorapidity range $|\eta|<2$, was carried out using the ALICE detector. Measurements were obtained for three event classes: inelastic, non-single diffractive and events with at least one charged particle in the pseudorapidity interval $|\eta|<1$. The use of an improved track-counting algorithm combined with ALICE's measurements of diffractive processes allows a higher precision compared to our previous publications. A KNO scaling study was performed in the pseudorapidity intervals $|\eta|<$ 0.5, 1.0 and 1.5. The data are compared to other experimental results and to models as implemented in Monte Carlo event generators PHOJET and recent tunes of PYTHIA6, PYTHIA8 and EPOS.

We present results on transverse momentum ($p_{\rm T}$) and rapidity ($y$) differential production cross sections, mean transverse momentum and mean transverse momentum square of inclusive J/$\psi$ and $\psi(2S)$ at forward rapidity ($2.5<y<4$) as well as $\psi(2S)$-to-J/$\psi$ cross section ratios. These quantities are measured in pp collisions at center of mass energies $\sqrt{s}=5.02$ and 13 TeV with the ALICE detector. Both charmonium states are reconstructed in the dimuon decay channel, using the muon spectrometer. A comprehensive comparison to inclusive charmonium cross sections measured at $\sqrt{s}=2.76$, 7 and 8 TeV is performed. A comparison to non-relativistic quantum chromodynamics and fixed-order next-to-leading logarithm calculations, which describe prompt and non-prompt charmonium production respectively, is also presented. A good description of the data is obtained over the full $p_{\rm T}$ range, provided that both contributions are summed. In particular, it is found that for $p_{\rm T}>15$ GeV/$c$ the non-prompt contribution reaches up to 50% of the total charmonium yield.

The production of $\pi^{\pm}$, $\rm{K}^{\pm}$, $\rm{K}^{0}_{S}$, $\rm{K}^{*}(892)^{0}$, $\rm{p}$, $\phi(1020)$, $\Lambda$, $\Xi^{-}$, $\Omega^{-}$, and their antiparticles was measured in inelastic proton-proton (pp) collisions at a center-of-mass energy of $\sqrt{s}$ = 13 TeV at midrapidity ($|y|<0.5$) as a function of transverse momentum ($p_{\rm{T}}$) using the ALICE detector at the CERN LHC. Furthermore, the single-particle $p_{\rm{T}}$ distributions of $\rm{K}^{0}_{S}$, $\Lambda$, and $\overline{\Lambda}$ in inelastic pp collisions at $\sqrt{s}$ = 7 TeV are reported here for the first time. The $p_{\rm{T}}$ distributions are studied at midrapidity within the transverse momentum range $0\leq p_{\rm{T}}\leq20$ GeV/$c$, depending on the particle species. The $p_{\rm{T}}$ spectra, integrated yields, and particle yield ratios are discussed as a function of collision energy and compared with measurements at lower $\sqrt{s}$ and with results from various general-purpose QCD-inspired Monte Carlo models. A hardening of the spectra at high $p_{\rm{T}}$ with increasing collision energy is observed, which is similar for all particle species under study. The transverse mass and $x_{\rm{T}}\equiv2p_{\rm{T}}/\sqrt{s}$ scaling properties of hadron production are also studied. As the collision energy increases from $\sqrt{s}$ = 7 to 13 TeV, the yields of non- and single-strange hadrons normalized to the pion yields remain approximately constant as a function of $\sqrt{s}$, while ratios for multi-strange hadrons indicate enhancements. The $p_{\rm{T}}$-differential cross sections of $\pi^{\pm}$, $\rm{K}^{\pm}$ and $\rm{p}$ ($\overline{\rm{p}}$) are compared with next-to-leading order perturbative QCD calculations, which are found to overestimate the cross sections for $\pi^{\pm}$ and $\rm{p}$ ($\overline{\rm{p}}$) at high $p_{\rm{T}}$.

The first measurements of the production of muons and electrons from heavy-flavour hadron decays in Xe-Xe collisions at $\sqrt{s_{\rm NN}}$ = 5.44 TeV, using the ALICE detector at the LHC, are reported. The measurement of the nuclear modification factor $R_{\rm AA}$ is performed as a function of transverse momentum $p_{\rm T}$ in several centrality classes at forward rapidity ($2.5 < y <4$) and midrapidity ($\vert y \vert < 0.8$) for muons and electrons from heavy-flavour hadron decays, respectively. A suppression by a factor up to about 2.5 compared to the binary-scaled pp reference is observed in central collisions at both central and forward rapidities. The $R_{\rm AA}$ of muons from heavy-flavour hadron decays is compared to previous measurements in Pb-Pb collisions at $\sqrt{s_{\rm NN}}$ = 5.02 TeV. When the nuclear modification factors are compared in the centrality classes 0-10% for Xe-Xe collisions and 10-20% for Pb-Pb collisions, which have similar charged-particle multiplicity density, a similar suppression, with $R_{\rm AA} \sim 0.4$ in the $p_{\rm T}$ interval $4 < p_{\rm T} < 8$ GeV/$c$, is observed. The comparison of the measured $R_{\rm AA}$ values in the two collision systems brings new insights on the properties of the quark-gluon plasma by investigating the system-size and path-length dependence of medium-induced parton energy loss. The results of muons and electrons from heavy-flavour hadron decays provide new constraints to model calculations.