On 23rd November 2009, during the early commissioning of the CERN Large Hadron Collider (LHC), two counter-rotating proton bunches were circulated for the first time concurrently in the machine, at the LHC injection energy of 450 GeV per beam. Although the proton intensity was very low, with only one pilot bunch per beam, and no systematic attempt was made to optimize the collision optics, all LHC experiments reported a number of collision candidates. In the ALICE experiment, the collision region was centred very well in both the longitudinal and transverse directions and 284 events were recorded in coincidence with the two passing proton bunches. The events were immediately reconstructed and analyzed both online and offline. We have used these events to measure the pseudorapidity density of charged primary particles in the central region. In the range |$\eta$| < 0.5, we obtain dNch/deta = 3.10 $\pm$ 0.13 (stat.) $\pm$ 0.22 (syst.) for all inelastic interactions, and dNch/deta = 3.51 $\pm$ 0.15 (stat.) $\pm$ 0.25 (syst.) for non-single diffractive interactions. These results are consistent with previous measurements in proton-antiproton interactions at the same centre-of-mass energy at the CERN SppS collider. They also illustrate the excellent functioning and rapid progress of the LHC accelerator, and of both the hardware and software of the ALICE experiment, in this early start-up phase.

The first measurement of the ${\rm e}^{+}{\rm e}^{-}$ pair production at low lepton pair transverse momentum ($p_{\rm T,ee}$) and low invariant mass ($m_{\rm ee}$) in non-central Pb$-$Pb collisions at $\sqrt{s_{\rm NN}} = 5.02$ TeV at the LHC is presented. The dielectron production is studied with the ALICE detector at midrapidity ($|\eta_{\rm e}| < 0.8$) as a function of invariant mass ($0.4 \leq m_{\rm ee} < 2.7$ GeV/$c^2$) in the 50$-$70% and 70$-$90% centrality classes for $p_{\rm T,ee} < 0.1$ GeV/$c$, and as a function of $p_{\rm T,ee}$ in three $m_{\rm ee}$ intervals in the most peripheral Pb$-$Pb collisions. Below a $p_{\rm T,ee}$ of 0.1 GeV/$c$, a clear excess of ${\rm e}^{+}{\rm e}^{-}$ pairs is found compared to the expectations from known hadronic sources and predictions of thermal radiation from the medium. The $m_{\rm ee}$ excess spectra are reproduced, within uncertainties, by different predictions of the photon$-$photon production of dielectrons, where the photons originate from the extremely strong electromagnetic fields generated by the highly Lorentz-contracted Pb nuclei. Lowest-order quantum electrodynamic (QED) calculations, as well as a model that takes into account the impact-parameter dependence of the average transverse momentum of the photons, also provide a good description of the $p_{\rm T,ee}$ spectra. The measured $\sqrt{\langle p_{\rm T,ee}^{2} \rangle}$ of the excess $p_{\rm T,ee}$ spectrum in peripheral Pb$-$Pb collisions is found to be comparable to the values observed previously at RHIC in a similar phase-space region.

We present the charged-particle multiplicity distributions over a wide pseudorapidity range ($-3.4<\eta<5.0$) for pp collisions at $\sqrt{s}=$ 0.9, 7, and 8 TeV at the LHC. Results are based on information from the Silicon Pixel Detector and the Forward Multiplicity Detector of ALICE, extending the pseudorapidity coverage of the earlier publications and the high-multiplicity reach. The measurements are compared to results from the CMS experiment and to PYTHIA, PHOJET and EPOS LHC event generators, as well as IP-Glasma calculations.

The inclusive charged particle transverse momentum distribution is measured in proton-proton collisions at $\sqrt{s} = 900$ GeV at the LHC using the ALICE detector. The measurement is performed in the central pseudorapidity region $(|\eta|<0.8)$ over the transverse momentum range $0.15<p_{\rm T}<10$ GeV/$c$. The correlation between transverse momentum and particle multiplicity is also studied. Results are presented for inelastic (INEL) and non-single-diffractive (NSD) events. The average transverse momentum for $|\eta|<0.8$ is $\left<p_{\rm T}\right>_{\rm INEL}=0.483\pm0.001$ (stat.) $\pm0.007$ (syst.) GeV/$c$ and $\left<p_{\rm T}\right>_{\rm NSD}=0.489\pm0.001$ (stat.) $\pm0.007$ (syst.) GeV/$c$, respectively. The data exhibit a slightly larger $\left<p_{\rm T}\right>$ than measurements in wider pseudorapidity intervals. The results are compared to simulations with the Monte Carlo event generators PYTHIA and PHOJET.

We report measurements of the inclusive J/$\psi$ yield and average transverse momentum as a function of charged-particle pseudorapidity density ${\rm d}N_{\rm ch}/{\rm d}\eta$ in p-Pb collisions at $\sqrt{s_{\rm NN}}= 5.02$ TeV with ALICE at the LHC. The observables are normalised to their corresponding averages in non-single diffractive events. An increase of the normalised J/$\psi$ yield with normalised ${\rm d}N_{\rm ch}/{\rm d}\eta$, measured at mid-rapidity, is observed at mid-rapidity and backward rapidity. At forward rapidity, a saturation of the relative yield is observed for high charged-particle multiplicities. The normalised average transverse momentum at forward and backward rapidities increases with multiplicity at low multiplicities and saturates beyond moderate multiplicities. In addition, the forward-to-backward nuclear modification factor ratio is also reported, showing an increasing suppression of J/$\psi$ production at forward rapidity with respect to backward rapidity for increasing charged-particle multiplicity.

The pseudorapidity density and multiplicity distribution of charged particles produced in proton-proton collisions at the LHC, at a centre-of-mass energy $\sqrt{s} = 7$ TeV, were measured in the central pseudorapidity region |$\eta$| < 1. Comparisons are made with previous measurements at $\sqrt{s}$ = 0.9 TeV and 2.36 TeV. At $\sqrt{s}$ = 7 TeV, for events with at least one charged particle in |$\eta$| < 1, we obtain dNch/deta = 6.01 $\pm$ 0.01 (stat.) $^{+0.20}_{-0.12}$ (syst.). This corresponds to an increase of 57.6% $\pm$ 0.4% (stat.) $^{+3.6}_{-1.8}$% (syst.) relative to collisions at 0.9 TeV, significantly higher than calculations from commonly used models. The multiplicity distribution at 7 TeV is described fairly well by the negative binomial distribution.

The ratios of yields of anti-baryons to baryons probes the mechanisms of baryon-number transport. Results for $\bar{\rm p}/{\rm p}$, $\bar{\rm \Lambda}/{\rm \Lambda}$, $\rm\bar{\Xi}$$^{+}/{\rm \Xi}^{-}$ and $\rm\bar{\Omega}$$^{+}/{\rm \Omega}^{-}$ in pp collisions at $\sqrt{s} = 0.9$, 2.76 and 7 TeV, measured with the ALICE detector at the LHC, are reported. Within the experimental uncertainties and ranges covered by our measurement, these ratios are independent of rapidity, transverse momentum and multiplicity for all measured energies. The results are compared to expectations from event generators, such as PYTHIA and HIJING-B, that are used to model the particle production in pp collisions. The energy dependence of $\bar{\rm p}/{\rm p}$, $\bar{\rm \Lambda}/{\rm \Lambda}$, $\rm\bar{\Xi}$$^{+}/{\rm \Xi^{-}}$ and $\rm\bar{\Omega}$$^{+}/{\rm \Omega^{-}}$, reaching values compatible with unity for $\sqrt{s} = 7$ TeV, complement the earlier $\bar{\rm p}/{\rm p}$ measurement of ALICE. These dependencies can be described by exchanges with the Regge-trajectory intercept of $\alpha_{\rm {J}} \approx 0.5$, which are suppressed with increasing rapidity interval ${\rm \Delta} y$. Any significant contribution of an exchange not suppressed at large ${\rm \Delta} y$ (reached at LHC energies) is disfavoured.

We report about the properties of the underlying event measured with ALICE at the LHC in pp and p$-$Pb collisions at $\sqrt{s_{\rm NN}}=5.02$ TeV. The event activity, quantified by charged-particle number and summed-$p_{\rm T}$ densities, is measured as a function of the leading-particle transverse momentum ($p_{\rm T}^{\rm trig}$). These quantities are studied in three azimuthal-angle regions relative to the leading particle in the event: toward, away, and transverse. Results are presented for three different $p_{\rm T}$ thresholds (0.15, 0.5, and 1 GeV/$c$) at mid-pseudorapidity ($|\eta|<0.8$). The event activity in the transverse region, which is the most sensitive to the underlying event, exhibits similar behaviour in both pp and p$-$Pb collisions, namely, a steep increase with $p_{\rm T}^{\rm trig}$ for low $p_{\rm T}^{\rm trig}$, followed by a saturation at $p_{\rm T}^{\rm trig} \approx 5$ GeV/$c$. The results from pp collisions are compared with existing measurements at other centre-of-mass energies. The quantities in the toward and away regions are also analyzed after the subtraction of the contribution measured in the transverse region. The remaining jet-like particle densities are consistent in pp and p$-$Pb collisions for $p_{\rm T}^{\rm trig}>10$ GeV/$c$, whereas for lower $p_{\rm T}^{\rm trig}$ values the event activity is slightly higher in p$-$Pb than in pp collisions. The measurements are compared with predictions from the PYTHIA 8 and EPOS LHC Monte Carlo event generators.

The first measurements of the invariant differential cross sections of inclusive $\pi^0$ and $\eta$ meson production at mid-rapidity in proton-proton collisions at $\sqrt{s}=0.9$ TeV and $\sqrt{s}=7$ TeV are reported. The $\pi^0$ measurement covers the ranges $0.4<p_T<7$ GeV/$c$ and $0.3<p_T<25$ GeV/$c$ for these two energies, respectively. The production of $\eta$ mesons was measured at $\sqrt{s}=7$ TeV in the range $0.4<p_T<15$ GeV/$c$. Next-to-Leading Order perturbative QCD calculations, which are consistent with the $\pi^0$ spectrum at $\sqrt{s}=0.9$ TeV, overestimate those of $\pi^0$ and $\eta$ mesons at $\sqrt{s}=7$ TeV, but agree with the measured $\eta/\pi^0$ ratio at $\sqrt{s}=7$ TeV.

Inclusive transverse momentum spectra of primary charged particles in Pb-Pb collisions at $\sqrt{s_{_{\rm NN}}}$ = 2.76 TeV have been measured by the ALICE Collaboration at the LHC. The data are presented for central and peripheral collisions, corresponding to 0-5% and 70-80% of the hadronic Pb-Pb cross section. The measured charged particle spectra in $|\eta|<0.8$ and $0.3 < p_T < 20$ GeV/$c$ are compared to the expectation in pp collisions at the same $\sqrt{s_{\rm NN}}$, scaled by the number of underlying nucleon-nucleon collisions. The comparison is expressed in terms of the nuclear modification factor $R_{\rm AA}$. The result indicates only weak medium effects ($R_{\rm AA} \approx $ 0.7) in peripheral collisions. In central collisions, $R_{\rm AA}$ reaches a minimum of about 0.14 at $p_{\rm T}=6$-7GeV/$c$ and increases significantly at larger $p_{\rm T}$. The measured suppression of high-$p_{\rm T}$ particles is stronger than that observed at lower collision energies, indicating that a very dense medium is formed in central Pb-Pb collisions at the LHC.